Chullikkattil P Pradeep
Articles written in Journal of Chemical Sciences
Volume 118 Issue 4 July 2006 pp 311-317
A chiral Mn(IV) complex and its supramolecular assembly: Synthesis, characterization and properties
Chullikkattil P Pradeep Panthapally S Zacharias Samar K Das
The open air reaction of the chiral Schiff base ligand H2L, prepared by the condensation of L-phenylalaninol and 5-bromosalicylaldehyde, with MnII(CH3COO)2.4H2O yielded dark brown complex [MnIV L2]·0·5 DMF (1). Compound 1 was characterized by elemental analysis, IR, UV-visible, CD and EPR spectroscopy, cyclic voltammetry and room temperature magnetic moment determination. Single-crystal X-ray analysis revealed that compound 1 crystallises in the monoclinic
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