Articles written in Journal of Chemical Sciences
Volume 90 Issue 1 January 1981 pp 5-10 Inorganic and Analytical
New complexes of lanthanide perchlorates with di-
Infrared spectra indicate the coordination of all the available ether oxygens and the amide carbonyls in each of the ligands, to the metal ions. IR and conductance data show that the perchlorate groups in all the complexes are ionic.1H and13C NMR data support the IR data regarding the mode of coordination of ligands to the metal ions. Electronic spectral shapes have been interpreted in terms of nine, eight and ten coordination in DiGA, TriGA and TetGA complexes respectively.
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