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- Biswajit Sharangi
  
  Articles written in Journal of Chemical Sciences
- Volume 124 Issue 6 November 2012 pp 1377-1383
  
  Rhomboidal [Cu₄] coordination cluster from self-assembly of two asymmetric phenoxido-bridged Cu₂ units: Role of $\mu_{1,1}$-azido clips
  
  Avijit Sarkar Aloke Kumar Ghosh Moumita Pait Haridas Mandal Tufan Singha Mahapatra Biswajit Sharangi Mrinal Sarkar Debashis Ray
  
  More Details Abstract Fulltext PDF
  
  The coordination cluster [Cu₂(𝜇-OMe)($\mu_{1,1}$-N₃)(𝜇-bcp)(N₃)]₂ (1; Hbcp = 2,6-bis(2-benzoyl-4-chloro-phenylimino)-methyl)-4-methylphenol, forming a new member within the rapidly growing family of Cu₄ cluster complexes, has been synthesized and structurally characterized by X-ray crystallography. The complex crystallizes in the monoclinic system, space group P2₁/𝑐, with unit cell parameters a = 14.620(7) Å, b = 17.923(8) Å, c = 15.008(7) Å, 𝛽 = 115.815(14)° and Z = 2. It is the first example of a rhomboidal [Cu₄] compound formed from $\mu_{1,1}$-azido clipping of two methoxido bridged [Cu₂] complexes showing asymmetric coordination from benzophenone oxygen atoms and terminal azido groups.

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