Articles written in Journal of Chemical Sciences
Volume 87 Issue 6 June 1978 pp 215-217 Physical and Theoretical
The kinetics of oxidation of allyl alcohol by chloramine-T (CAT) in presence of 0·02 M hydrochloric acid and at a constant ionic strength (μ=0·5 M) have been studied polarographically at six different temperatures between 30°C and 45°C. The reaction shows first order dependence on concentration of chloramine-T. The energy and entropy of activation have been found to be 13·7 kcal mol−1 and −28·4 e.u. respectively.
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