Articles written in Journal of Chemical Sciences
Volume 93 Issue 4 May 1984 pp 741-751 Inorganic Chemistry
The structure and selected reactions of the title compounds are reviewed. Some highlights are as follows (L = conjugate base of phenylazoacetaldoxime). While PtL2 exist in cis and trans forms, PdL2 occurs only in the
Volume 95 Issue 1-2 July 1985 pp 159-167
Volume 102 Issue 3 June 1990 pp 195-202
Synthetic ferroverdins, NaFe11(RQ)3 afford trinuclear M[Fe(RQ)3]2 upon reaction with bivalent ions (M2+). A probable bonding mode is considered. Ferric ions oxidise ferroverdin to ferriverdin, FeIII(RQ)3. Both
Volume 104 Issue 3 June 1992 pp 351-360 Inorganic and Analytical
The reaction of Mn(CH3COO)3 2H2O with the carboxyl-rich ligand pyridine-2,6-dicarboxylic acid (H2L) in methanol affords a high-spin (
Volume 106 Issue 3 June 1994 pp 793-793
Volume 106 Issue 3 June 1994 pp 802-802
Volume 106 Issue 6 November 1994 pp 1341-1348
Reactions involving the coupled transfer of electrons and protons are called electroprotic reactions. In this article we briefly describe some of our experiences with electroprotic reaction as a tool for executing interesting chemical transformations.
Volume 111 Issue 3 June 1999 pp 469-477 Modern Trends In Inorganic Chemistry
The reaction of Schiff monobases of 2,6-diformyl-4-methylphenol with ruthenium(II) and osmium(II) has afforded a new family of orthometalated organometallics. Synthesis, characterization and reactivity are briefly discussed in this article.
Volume 115 Issue 5-6 October 2003 pp 333-339
The title transformations are oxygen atom transfer, twin isomerization and regiospecific imine oxidation.
Volume 120 Issue 1 January 2008 pp 87-93
The reaction of [RhCl2(HPhL)(PhL)] with MII(ClO4)2.6H2O in presence of alkali has furnished trinuclear [RhCl2(PhL)2]2M(H2O)$_2.$H2O (HPhL is phenylazobenzaldoxime; M = Mn, Co, Ni). A similar reaction with MI(PPh3)2NO3 yielded binuclear [RhCl2(PhL)2]M(PPh3)2 (M = Cu, Ag). In these molecules the oximato group acts as a bridge between RhIII (bonded at N) and MII or MI (bonded at O). In structurally characterized [RhIIICl2(PhL)2]2Mn(H2O)2.H2O the centrosymmetric distorted octahedral MnO6 coordination sphere is spanned by four oximato oxygen atoms and two water molecules lying in trans position. In the lattice the neighbouring molecules are held together by H2O$\cdots$H2O$\cdots$H2O hydrogen bonds generating infinite zigzag chains. The manganese atoms lie parallel to the C-axis, the shortest Mn…Mn distance being 7.992 Å. Magnetic exchange interactions if any are small as seen in room temperature magnetic moments. The manganese system displays a strong EPR signal near 𝑔 = 2.00. In the complex [RhCl2(PhL)2]Cu(PPh3)2 the copper atom is coordinated to two oximato oxygen atoms and the two phosphorus atoms in a distorted tetrahedral geometry. The softness of the phosphine ligand is believed to sustain the stable coordination of hard oximato oxygen to soft CuI. The coordination sphere of the RhIII atom in both the complexes is uniformly
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