Articles written in Journal of Chemical Sciences
Volume 114 Issue 4 August 2002 pp 431-442
Intervalence charge transfer properties were studied for a set of mixed valence complexes incorporating Ru(III) and Fe(II)-centres linked by various saturated and unsaturated bridging ligands (BL). Studies reveal that degree of ground state electronic interaction and coupling between Ru(III) and Fe(II)-centrescanbe attenuated by changing the nature of the bridging ligand. Further, inclusion of the bridging ligand with interrupted π-electron system in a β-CD cavity initiate an optical electron transfer from Fe(II) to Ru(III) which is otherwise not observed.
Volume 135, 2023
Continuous Article Publishing mode
Click here for Editorial Note on CAP Mode