• AYDINLI E

      Articles written in Journal of Chemical Sciences

    • Homogeneous catalyst containing Pd in the reduction of aryl azides to primary amines

      CANTOPCU E AYDINLI E GOKSU H

      More Details Abstract Fulltext PDF

      Commercially available dichloro[2,2-bis(diphenylphosphino)-1,1-binaphthyl]palladium(II)(BINAP.PdCl2) homogeneous catalyst was used for the reduction of aryl azides to primary amines. Thereactions were carried out in water and yields above 95% were obtained in a short time. Sodium borohydridewas used as the reducing reagent. A number of aryl azide derivatives have been converted into primaryamines, thanks to the hydrogen gas released by sodium borohydride with the help of water and catalyst.

      Synopsis Commercially available dichloro[2,2-bis(diphenylphosphino)-1,1-binaphthyl]palladium(II) (BINAP.PdCl2) homogeneous catalyst was used for the reduction of aryl azides to primary amines. The reactions were carried out in water and yields above 95% were obtained in a short time. Sodium borohydride was used as the reducing reagent. A number of aryl azide derivatives have been converted into primary amines, thanks to the hydrogen gas released by sodium borohydride with the help of water and catalyst.

  • Journal of Chemical Sciences | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2021-2022 Indian Academy of Sciences, Bengaluru.