Articles written in Journal of Chemical Sciences
Volume 118 Issue 3 May 2006 pp 243-248
Hydrothermal syntheses and single crystal structural characterization of M(H2O)6(OPTA)2 [M = Co(II), Ni(II), Zn(II); OPTA = 1-oxopyridinium-2-thioacetato]
S Kumaresan P Ramadevi R D Walsh A Mcaneny C H Lake
A new class of compounds of the family M(H2O)6(OPTA)2 (where M = Co(II), Ni(II), and Zn(II); OPTA = 1-oxopyridinium-2-thioacetato) was prepared from the appropriate metal acetates, 1-oxo-pyridinium-2-thioacetic acid (OPTAH), and potassium hydroxide in hydrothermal media and structurally characterized. The structure is constructed from M(H2O)62+ and two anions of OPTAH (C7H6NO3S) linked through hydrogen bonding into an extended network.
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