• U R Ghodake

      Articles written in Bulletin of Materials Science

    • Microstructure studies on Ti4+- and Zr4+-substituted Li-Zn ferrites

      R S Patil S S Suryavanshi S V Kakatkar A M Sankpal U R Ghodake S A Patil S R Sawant

      More Details Abstract Fulltext PDF

      XRD and microstructure studies were carried out on Ti4+ and Zr4+-substituted Li-Zn ferrites prepared by standard ceramic technique. All the ferrite compositions exhibit single phase formation. The lattice parametera increases linearly with the content of Zn2+Zr4+ and Zn2+Ti4+, which is attributed to the ionic volumes of the cations involved. With substitution by Zr4+ the average size decreases, while with substitution by Ti4+ the grain size increases. In both the series grain size varies with the composition. Excess substitution of Zr4+ (x>0·4) leads to the formation of secondary images and discontinuous grain growth. Both Zr4+ and Ti4+ compositions obey Kurtz theory.

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