Articles written in Bulletin of Materials Science
Volume 13 Issue 4 September 1990 pp 293-300
Electrical transport in magnesium aluminate
Tom Mathews K T Jacob J P Hajra
The conductivity of MgAl2O4 has been measured at 1273, 1473 and 1673 K as a function of the partial pressure of oxygen ranging from 105 to 10−14 Pa. The MgAl2O4 pellet, sandwiched between two platinum electrodes, was equilibrated with a flowing stream of either Ar + O2, CO + CO2 or Ar + H2 + H2O mixture of known composition. The gas mixture established a known oxygen partial pressure. All measurements were made at a frequency of 1 kHz. These measurements indicate pressure independent ionic conductivity in the range 1 to 10−14 Pa at 1273 K, 10−1 to 10−12 Pa at 1473 K and 10−1 to 10−4 Pa at 1673 K. The activation energy for ionic conduction is 1·48 eV, close to that for self-diffusion of Mg2+ ion in MgAl2O4 calculated from the theoretical relation of Glyde. Using the model, the energy for cation vacancy formation and activation energy for migration are estimated.
Volume 43 All articles Published: 29 October 2020 Article ID 0291
Electrochemical studies on wafer-scale synthesized silicon nanowalls for supercapacitor application
ANIL K BEHERA C LAKSHMANAN R N VISWANATH C PODDAR TOM MATHEWS
Silicon-based supercapacitors are highly essential for the utilization of supercapacitor technology in consumer electronics, owing to their on-chip integration with the well-established complementary metal–oxide–semiconductor-related fabrication technology. In this study, silicon nanowalls were carved on commercially available silicon wafers by using a facile, low-cost and complementary metal–oxide–semiconductor compatible method of metal (silver)-assisted chemical etching. The electron microscopic studies of the carved out silicon nanowalls reveal that they are smooth, single crystalline and vertically aligned to their base silicon wafer. Raman and ATR-FTIR spectroscopy confirmthat the surface of the silicon nanowalls has Si–O–Si bonded structures. Cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) studies were carried out in the organic electrolyte tetraethylammonium tetrafluroborate(NEt$_4$BF$_4$) in propylene carbonate (PC). It is evident from both the CV and GCD studies that the silicon nanowalls exhibit redox peaks arising from the silver-related deep-level trap state in silicon in contact with adsorbed water and also from the oxidation of silicon and its hydrides by the water present in the electrolyte. The presence of silver in silicon nanowalls and water in the electrolyte are considered to be due to the minute amount of silver left over during its removal by HNO$_3$, owing to the bunching of nanowalls and the highly moisture sensitive nature of the electrolyte, respectively. The influenceof such redox peaks on capacitance and cycle life are discussed.
Volume 46, 2023
Continuous Article Publishing mode
Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020
Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020
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