• S Bhattacherjee

      Articles written in Bulletin of Materials Science

    • Variation of electrical properties in sepiolite during dehydration

      S Lokanatha S Bhattacherjee

      More Details Abstract Fulltext PDF

      The dielectric constant (K), loss (tanδ) andac conductivity of a sepiolite sample have been measured as a function of frequency in the range 102-107 Hz and in the temperature region 30–400°C. Thedc conductivities of hot pressed pellets were measured in the temperature range 30–550°C.K and tanδ of these samples decrease with increasing frequency. Results of these measurements have been correlated with the structural transformation accompanying dehydration, making use ofdta, ir and x-ray data. The moderately large value of activation energy (∼ 2·2 eV) in the intrinsic range suggests that the conduction process is most probably associated with ions.

    • Thermal transformation in a chrysotile asbestos

      A K Datta B K Samantaray S Bhattacherjee

      More Details Abstract Fulltext PDF

      Structural changes accompanying thermal transformation in a chrysotile asbestos sample of Indian origin upto a temperature of 900°C have been investigated by x-ray method. The changes in lattice parameters have been systematically measured by applying a least square refinement technique and the crystallite size and strain defects at different stages have been estimated by line profile analysis of the diffraction peaks. The present study also confirms the earlier results on stepwise transformation of chrysotile fibres. This sequence of transformation has been explained assuming two different types of crystallites as reported in kaolinite.

    • Dehydration and phase transformation in chrysotile asbestos—A radial distribution analysis study

      A K Datta B K Mathur B K Samantaray S Bhattacherjee

      More Details Abstract Fulltext PDF

      Radial distribution analysis of x-ray intensities diffracted by chrysotile samples untreated and treated at different temperatures upto 900°C has been carried out. Interatomic distances, coordination numbers, mean square displacements and the interatomic coupling constants for different pairs of atoms have been calculated from the radial distribution curves. The interatomic distances and octahedral co-ordination number is found to decrease marginally upto 640°C and thereafter decrease steadily upto 800°C. The hydroxyl water is completely expelled from the structure and the original chrysotile structure breaks down. The entire process of dehydration has been interpreted in terms of RDF data.

  • Bulletin of Materials Science | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2017-2019 Indian Academy of Sciences, Bengaluru.