• SULAWAN KAOWPHONG

      Articles written in Bulletin of Materials Science

    • Effect of pH on formation of Ti-O-based photocatalysts prepared by green chemistry and their photocatalytic activities

      SUMETHA SUWANBOON SULAWAN KAOWPHONG PONGSATON AMORNPITOKSUK

      More Details Abstract Fulltext PDF

      In this study, the effect of water extract of wood ash (WEWA) as a reagent from waste was studied on the formation of Ti-O-based photocatalysts. The pH of the reaction solution was controlled by varying the volume of WEWA. In an acidic condition, the products were identified as TiO$_2$, but the K$_2$Ti$_6$O$_{13}$/TiO$_2$ was formed when pH of the solution was ${\ge}$6. Photocatalytic activities of calcined products were investigated through the degradation of methylene blue (MB,cationic dye) and reactive orange (RO, anionic dye) solutions. The TiO$_2$ prepared from acid condition degraded MB and RO under blacklight irradiation but not under visible-light irradiation, while the K$_2$Ti$_6$O$_{13}$/TiO$_2$ degraded MB undervisible-light irradiation through a dye-sensitized photocatalytic mechanism but could not degrade RO. Addition of MB into RO solution improved the photocatalytic degradation of RO by K$_2$Ti$_6$O$_{13}$/TiO$_2$ because MB could be adsorbed on thesurface of K$_2$Ti$_6$O$_{13}$/TiO$_2$ and promoted the MB-sensitized photocatalytic process.

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