Articles written in Bulletin of Materials Science
Volume 28 Issue 2 April 2005 pp 131-136 Fly Ash
The reaction between fly ash (FA) and lime is extensively exploited for the manufacture of building bricks, blocks and aggregates. To get a better idea of this reaction, FA from different sources were mixed in different ratios with lime and compacted. The compacts were treated both by ordinary water and hydrothermal curing to promote lime bearing hydrate bond formation e.g. CaO–SiO2–H2O (C–S–H), CaO–Al2O3–H2O (C–A–H) etc. The decrease in free lime content in these compacts was measured as a function of curing time and curing process. This drop in this content was correlated to the chemical composition of the fly ashes. The mathematical relationships between free lime remaining in the compacts after its maximum decrease in concentration and lime binding modulus (a ratio between the amount of added lime and the total amount of lime binding constituents present in FA) for both types of curing were developed. Further, the rate of decrease in free CaO content under both types of curing conditions was compared from kinetic study. From this study the orders of the reactions and rate constants were found out.
Volume 28 Issue 7 December 2005 pp 697-702 Composites
Four different varieties of class F fly ashes, collected from different sources from the state of West Bengal (India) were mixed with lime in 9 : 1 wt ratio, followed by compaction of the mixes. The compacts were subjected to steam curing to develop an optimum strength by the reaction between fly ash and lime. The steam cured compacts were heated at different elevated temperatures and free lime content, compressive strength, bulk density and water absorption tendency of these compacts were measured and FTIR spectral changes were studied as a function of the heating temperatures. Kinetics of thermal dehydration of the compacts was also studied from thermogravimetric measurements under non-isothermal condition to ascertain the order of dehydration process and the associated activation energy.
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