S M Yusuf
Articles written in Bulletin of Materials Science
Volume 34 Issue 4 July 2011 pp 899-905
Erbium (Er) and lanthanum (La) substituted BiFeO3 (BFO) ceramics have been prepared through conventional solid solution route. X-ray diffraction data indicated a gradual phase transition from rhombohedral to monoclinic structure in Bi0.9–𝑥 La0.1Er𝑥 FeO3 (𝑥 = 0.05, 0.07 and 0.1) (BLEFO𝑥 = 0.05, 0.07,0.1) ceramics. Differential thermal analysis (DTA) measurements of BFO samples showed a ferroelectric transition at 835°C, whereas it is shifted to 792°C for BLEFO𝑥 = 0.1. The Raman spectra of BLEFO𝑥 = 0.05,0.07,0.1 samples showed the shift of Raman modes to higher wavenumbers and suppression of A1 modes indicating decrease in ferroelectricity. The Raman spectra also indicated the structural transformation due to Er and La substitution in BFO. On subsequent erbium doping, the intrinsic dielectric constant is found to decrease from 68 (for pure BFO) to 52 for BLEFO𝑥 = 0.05 to 43 for BLEFO𝑥 = 0.07 but increased to 89 for BLEFO𝑥 = 0.1 when compared to pure BFO. The increase in Er content resulted in the increase in spontaneous magnetization (0.1178 emu/g at 8T for BLEFO𝑥 = 0.1) due to collapse of spin cycloid structure. Ferroelectric remnant polarization of BLEFO𝑥 = 0.05 and BLEFO𝑥 = 0.07 decreases when compared to pure BFO while small remnant polarization (close to paraelectric behaviour) is evident for BLEFO𝑥 = 0.1.
Volume 37 Issue 4 June 2014 pp 815-821
Alloys of Fe–Si–B with varying compositions of Mn were prepared using high energy planetary ball mill for maximum duration of 120 h. X-ray diffraction (XRD) analysis suggests that Si gets mostly dissolved into Fe after 80 h of milling for all compositions. The residual Si was found to form an intermetallic Fe3Si. The dissolution was further confirmed from the field emission scanning electron microscopy/energy dispersive X-ray analysis (FE-SEM/EDX). With increased milling time, the lattice parameter and lattice strain are found to increase. However, the crystallite size decreases from micrometer (75–95 𝜇m) to nanometer (10–20 nm). Mössbauer spectra analysis suggests the presence of essentially ferromagnetic phases with small percentage of super paramagnetic phase in the system. The saturation magnetization (𝑀s), remanance (𝑀r) and coercivity (𝐻c) values for Fe–0Mn sample after 120 h of milling were 96.4 Am2/kg, 11.5 Am2/kg and 12.42 k Am-1, respectively. However, for Fe–10Mn–5Cu sample the 𝑀s, 𝐻c and 𝑀r values were found to be 101.9 Am2/kg, 10.98 kA/m and 12.4 Am2/kg, respectively. The higher value of magnetization could be attributed to the favourable coupling between Mn and Cu.
Volume 43, 2020
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Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020
Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020
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