Articles written in Bulletin of Materials Science
Volume 28 Issue 2 April 2005 pp 103-108 Ceramics and Glasses
Different solvent systems in combination with three different dispersants were tried to find out the suitable solvent–dispersant combination, which give optimum dispersion of PSZ. Based on sedimentation, viscosity and rheology characteristics, zeotropic ethanol : xylene with a ratio of 50 : 50 along with 0.5 wt% phosphate ester was found to be the best solvent and dispersant combination. Optimized tape casting slurry was prepared using PEG 600 and BBP as plasticizers and PVB as the binder. Cyclohexanone was used as the homogenizer. The optimized slurry composition with 58% solid loading exhibited shear-thinning pseudoplastic rheological behaviour. Y–PSZ tapes of ∼ 50 𝜇m thickness free from visible defects were cast with a green tape density of 55%.
Volume 30 Issue 4 August 2007 pp 333-338 Electrical Properties
The present study focuses on critical factors limiting single-phase formation of Ba2Ti9O20 (2 : 9). Apart from 2 : 9, other polytitanates that are richer in Ti or Ba could also be prepared as single-phase material without any stabilizing agent through chemical co-precipitation. 2 : 9 is found to be a stoichiometric compound and even 0.5% excess Ti or Ba leads to multiphase formation. Single-phase 2 : 9 could be achieved even through solid-state route without the addition of stabilizing agents using high purity raw materials. The present results do not agree with existing hypotheses viz. diffusion, high surface and nucleation energy, potential barrier, non-stoichiometry etc as critical factors limiting formation of 2 : 9 as single-phase material.
Volume 44, 2021
Continuous Article Publishing mode
Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020
Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020
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