-
- Home
- Journals
- Bulletin of Materials Science
-
R Nithya
Articles written in Bulletin of Materials Science
-
-
Volume 29 Issue 2 April 2006 pp 173-179 Precursors
Synthesis and characterization of sodium alkoxides
K Chandran R Nithya K Sankaran A Gopalan V Ganesan
Alcohol route is being adopted for cleaning sodium from sodium-wetted small components of coolant circuits of fast reactors. For better understanding of sodium–alcohol reactions and their energetics, the data on thermo-chemical properties such as heats of sodium–alcohol reactions, heats of dissolution, heat capacities, thermal decomposition behaviour, etc of their end products are essential. In order to generate such data, high purity sodium alkoxides, viz. sodium methoxide, sodium ethoxide and sodium 𝑛-propoxide, were prepared by reacting sodium metal with respective alcohol. These compounds were characterized using X-ray diffraction technique and IR spectroscopy. The elemental analysis was carried out by CHNS analyser and atomic emission spectroscopy. Normal chain sodium alkoxides were found to exhibit tetragonal crystal structure. Crystal structures of sodium ethoxide and sodium 𝑛-propoxide are reported for the first time. The IR spectrum of sodium 𝑛-propoxide is also reported for the first time.
-
-
Bulletin of Materials Science
Volume 46, 2023
All articles
Continuous Article Publishing mode
-
Bulletin of Materials Science | News
-
Dr Shanti Swarup Bhatnagar for Science and Technology
Posted on October 12, 2020Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020 -
Editorial Note on Continuous Article Publication
Posted on July 25, 2019Click here for Editorial Note on CAP Mode
-