P N Kotru
Articles written in Bulletin of Materials Science
Volume 8 Issue 5 December 1986 pp 547-555
Results obtained on characterization of lanthanum tartrate crystals, grown by the gel method, using chemical analysis, x-ray and electron diffraction, infra-red and mass spectroscopy are reported. The thermal behaviour is studied using DTA, TGA and DTG. The decomposition pattern is reported to be typical of a hydrated metal tartrate. Kinetic parameters like order of reaction, frequency factor and activation energy are evaluated. Contracting cylinder kinetic model is found to be the best fit for the decomposition processes involved. Magnetic susceptibility measurements indicate the material to be diamagnetic.
Volume 20 Issue 8 December 1997 pp 1089-1096
Thermal behaviour of gel-grown pure and mixed rare earth tartrates of yttrium and samarium is investigated using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The thermal behaviour suggests that the materials are unstable at lower energies and pass through various stages of decomposition, decomposing to respective rare earth oxides which remain stable on further heating. It is estimated that both pure yttrium and pure samarium tartrate crystals carry eight waters of hydration, while mixed yttrium samarium tartrate crystals carry six waters of hydration. Critical examination of TG and DSC curves shows that the initial decompositions are endothermic and the latter are exothermic. Thermal kinetics of these materials has been worked out using Horowitz-Metzger, Piloyan-Novikova and Coats-Redfern equations. Application of these equations to these materials yields values of activation energy, order of reaction and frequency factor which are in reasonably good agreement.
Volume 45, 2022
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Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020
Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020
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