• O P Thakur

      Articles written in Bulletin of Materials Science

    • Dielectric and microstructural behaviour of strontium titanate borosilicate glass ceramic system

      O P Thakur Devendra Kumar O M Parkash Lakshman Pandey

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      65(SrO·TiO2)−35(2SiO2·B2O3) wt% glass was synthesized. Differential thermal analysis study shows one exothermic peak which shifts towards higher temperature with increasing heating rate. Glass ceramics prepared by controlled crystallization of strontium titanate borosilicate glass produce uniform distribution of crystallites in a glassy matrix. Attempt was made to crystallize strontium titanate phase in this glass ceramic. Different phases precipitated out during ceramization have been identified by X-ray diffraction. It appears that due to high reactivity of SrO with B2O3, strontium borate crystallizes as principal phase followed by TiO2 (rutile) and Sr3Ti2O7 phases. Dielectric constant of these glass ceramics was observed to be more or less temperature independent over wide range of temperatures with low values of dielectric constant and dissipation factor.

    • Effect of 1 wt% CoO addition on dielectric and microstructural behaviour of (SrO·TiO2)-(2SiO2·B2O3) glass and glass ceramic

      O P Thakur Devendra Kumar O M Parkash Lakshman Pandey

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      Glass of the nominal composition 64 wt%(SrO·TiO2)·35 wt%(2SiO2·B2O3)-1 wt%(CoO) was prepared. The glass samples were subjected to heat treatment at 900 and 950 C. The phase progression in these glass ceramics from X-ray diffraction studies shows the formation of Sr2B2O5 as primary crystalline phase followed by rutile (TiO2), Sr3Ti2O7, SrB2Si2O8 and Sr3B2SiO8 as secondary phases. The first DTA exothermic peak of glass corresponds to the crystallization of Sr2B2O5, rutile and Sr3Ti2O7 phase while second crystallization peak may be assigned to the formation of SrB2Si2O8 and Sr3B2SiO8 phases. From microstructure studies we find that strontium borate grows with larger grain size whereas the other phases like Sr3Ti2O7, TiO2 appear smaller in size. Cobalt oxide content in the strontium titanate borosilicate glass ceramic gives the thermal stability to dielectric behaviour and decreases the dielectric loss.

    • Crystallization and microstructural behaviour of strontium titanate borosilicate glass ceramics with Bi2O3 addition

      O P Thakur Devendra Kumar Om Parkash Lakshman Pandey

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      Glasses in the system (65 −x) [SrO·TiO2] − (35) [2SiO2·B2O3] − (x) [Bi2O3] wherex = 1, 5, 10 (wt%) prepared by melting in alumina crucible (1375–1575 K), were subjected to different heat treatment schedules followed by DTA studies. Crystallization study showed the formation of Sr2B2O5 as major phase at low temperature (≈950°C) heat treatment. At high temperatures, TiO2 and SrTiO3 with or without Sr2B2O5 crystallize out depending on heat treatment. In this paper, the influence of variation in composition, thermal treatment on the nature of crystallizing phases as well as on the resulting microstructures are investigated through XRD, IR and SEM. Uniform crystallization was achieved by suitable addition of Bi2O3 and proper heat treatment.

    • Structural, dielectric and magnetoelectric coupling analysis in SrBi$_2$Nb$_2$O$_9$–CoFe$_2$O$_4$ composites

      PRACHI CHAUDHARY SAMIKSHA DABAS MANISH KUMAR ARVIND KUMAR O P THAKUR

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      Ferroelectric–magnetic composites of SrBi$_2$Nb$_2$O$_9$–CoFe$_2$O$_4$ (SBN–CFO) were synthesized via conventional solid state reaction route. The powder X-ray diffraction, Raman spectroscopy and scanning electron microscopy measurements confirm the existence of two chemically separated phases and phase purity in the SBN–CFO composites. Magnetization measurements confirm the enhanced values of the magnetic parameters. The change in the area of theferroelectric P vs. E loops with frequency confirms the enhanced ferroelectric nature of the SBN–CFO composites. The quantified maximum values of magnetoelectric coefficient ($\alpha$) are observed from the $P$ vs. $E$ loop measurements in the influence of applied magnetic field and found to be 4.475 mV cm$^{-1}$ Oe$^{-1}$ at 688 Oe for SBN–0.1CFO and 3.389 mV cm$^{-1}$ Oe$^{-1}$ at 1000 Oe for SBN–0.2CFO composites, respectively. The shifting in the peaks of temperature-dependent dielectric maxima towards the higher temperature side confirms the relaxor behaviour in the SBN–CFO composite samples.

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      Posted on October 12, 2020

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