• M Priya

      Articles written in Bulletin of Materials Science

    • Electrical conductivity measurements on gel grown KDP crystals added with urea and thiourea

      M Priya C M Padma T H Freeda C Mahadevan C Balasingh

      More Details Abstract Fulltext PDF

      Pure and impurity added (with urea and thiourea) KDP single crystals were grown by the gel method using silica gels. Electrical conductivity measurements were carried out along both the unique axis and perpendicular directions at various temperatures ranging from 30 to 140°C by the conventional two-probe method. The present study shows that the conductivity in KDP crystals, for both the impurities considered, increases with the increase in impurity concentration and temperature. Activation energies were also determined and reported.

    • Optical and magnetic properties of Yb ion-doped cobalt-based ZnO nanoparticles for DMS applications

      T Thangeeswari M Priya J Velmurugan N Padmanathan

      More Details Abstract Fulltext PDF

      Well-crystalline structured ZnO nanoparticles with cobalt (Co) and ytterbium (Yb) multiple ions doping were successfully synthesized by the chemical precipitation technique. The structures, optical and magnetic properties of the samples were analysed with X-ray diffraction (XRD), UV–visible spectroscopy and magnetic measurements, respectively. In the XRD pattern of the pure ZnO and Yb co-doped samples, the formation of highly crystalline phase of pure ZnO was observed even at high Yb concentration. UV–vis spectra show a strong UV absorbance for all the samples with different absorbance maxima. Magnetic characterizations have shown that the sample with 1% Yb co-doped ZnO: Co nanoparticles exhibited a clear ferromagnetic (FM) behaviour at room temperature. The X-ray photoelectron spectral peaks for Yb 4f ions reveal Yb occupation of both Yb3+ as well as Yb2+ states. Hence, it can be confirmed that a clear FM behaviour at room temperature was exhibited by an imbalanced valence state of Yb that strongly interacted with the Co2+. When compared to the Co-doped ZnO, Yb co-doped ZnO exhibits a clear ferromagnetism at room temperature with high coercivity due to the contribution of both 3d and 4f exchange interaction with the host matrix.

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      Posted on October 12, 2020

      Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
      Chemical Sciences 2020

      Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
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      Posted on July 25, 2019

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