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Volume 45 All articles Published: 20 July 2022 Article ID 0137
Two tetraphenylethylene-based fluorescent conjugated microporous polymers (TTTPT and TTDAT) were obtained by the Friedel-Crafts polymerization reactions catalysed by CH$_3$SO$_3$H. In virtue of containing tetraphenylethylene,triphenylamine and s-triazine units in their porous skeletons, the resulting TTTPT and TTDAT show excellent fluorescence sensing performance for trinitrophenol (TNP) with high quenching coefficients of 1.66 ${\times}$ 10$^4$ and 1.31 ${\times}$ 10$^5$ l mol$^{–1}$, respectively. TTDAT can also sense to dinitrophenol (DNP) with the Ksv of 2.70 ${\times}$ 10$^4$ l mol$^{–1}$. The fluorescent quenching mechanisms of TTTPT and TTDAT for selective detecting TNP attribute to conventional photoinduced electron-transfer mechanism, absorption competition quenching mechanism and/or the resonant energy transfer mechanism.
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Bulletin of Materials Science
Volume 46, 2023
All articles
Continuous Article Publishing mode
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Bulletin of Materials Science | News
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Dr Shanti Swarup Bhatnagar for Science and Technology
Posted on October 12, 2020Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020 -
Editorial Note on Continuous Article Publication
Posted on July 25, 2019Click here for Editorial Note on CAP Mode
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