HAWRAA SABAH HREO
Articles written in Bulletin of Materials Science
Volume 45 All articles Published: 18 October 2022 Article ID 0205
HAWRAA SABAH HREO ARAA MEBDIR HOLI ASLA ABDULLAH AL-ZAHRANI ASMAA KADIM AYAL M R ALMAMARI
The synthesis of bismuth (III) sulphide (Bi$_2$S$_3$)-sensitized titanium dioxide nanotubes arrays (TiO$_2$ NTAs) was carried out using the SILAR (successive ionic layer adsorption and reaction) method. The effect of different cycles onthe performance of a photoanode made of Bi$_2$S$_3$/TiO$_2$ NTAs in photoelectrochemical cells was investigated. Fieldemission scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction (XRD), Fourier transform infrared spectroscopy and UV–visible spectroscopy were used to investigate Bi$_2$S$_3$/TiO$_2$ NTs morphological, elemental composition, structural and optical absorption, respectively. TiO$_2$ nanotubes had a tetragonal crystal structure,whereas Bi$_2$S$_3$ had an orthorhombic crystal structure, according to XRD measurements. Absorbance spectra showed that the absorbance edges shifted towards longer wavelengths as the number of cycles increased, showing that the optical properties had significantly improved following deposition. Bi$_2$S$_3$/TiO$_2$ NTAs photoanode was proposed as a viable alternative photoanode in photoelectrochemical applications. The photocurrent density of the Bi$_2$S$_3$/TiO$_2$ NTAs composite film grew first, then declined as the number of Bi$_2$S$_3$ deposition cycles increased. After three cycles of deposition of Bi$_2$S$_3$, the Bi$_2$S$_3$/TiO$_2$ composite films displayed the highest photoelectrochemical characteristics. The photocurrent density of Bi$_2$S$_3$-3Cy/TiO$_2$ NTAs was 1.427 mA cm$^{–2}$, about four times that of plain TiO$_2$ NTAs. The Bi$_2$S$_3$/TiO$_2$ NTAs photoanode was offered as a feasible alternative photoanode in photoelectrochemical applications based on the findings of this study.
Volume 46, 2023
All articles
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Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020
Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020
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