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G Vijaya Prakash
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Volume 22 Issue 2 April 1999 pp 121-127 Glasses
Rare earth fluorescence in NASICON type phosphate glass, Na3TiZnP3O12
G Vijaya Prakash P Nachimuthu M Vithal R Jagannathan
The emission spectra of Pr3+, Eu3+ and Dy3+ doped in NASICON type phosphate glass, Na3TiZnP3O12 (NTZP) are studied. The dopant rare earth ions occupy sites with 8–9 coordination in a highly covalent environment. For Pr3+ ion, calculated and observed branching ratios for lasing transitions3
P 0→3H 4,6 agree well and found to be 0·64 and 0·24, respectively. The emissions of Pr3+ show strong temperature dependence on account of Boltzmann population of the higher excited states at room temperature. The excitation spectrum of Eu3+ gives rise to phonon assisted side band for5D 2←7F 0 transition at higher energy side with a phonon energy maximum of 1022 cm−1 and an electron phonon coupling strength (g ) of 0·018. The value of phonon energy maximum agrees with infrared spectral data. The results show that observation of high energy emissions in phosphate glasses require much higherg values. The red/orange and yellow/blue transitions of Eu3+ and Dy3+, respectively show that the Eu3+ occupy more distorted site than Dy3+.
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Bulletin of Materials Science
Volume 46, 2023
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