Articles written in Bulletin of Materials Science
Volume 34 Issue 1 February 2011 pp 25-28
Aqueous colloids of graphene oxide nanosheets were produced from exfoliation of graphite oxide using a magnetic stirrer and heat treatment in the absence of ultrasonication. Laser particle measurements showed that the particle size distribution of graphite oxide dispersed in de-ionized water was significantly influenced by treatment time indicating an increasing exfoliation level of graphite oxide. Atomic force microscopy (AFM) confirmed that single-layer graphene oxide nanosheets with a thickness of ∼1 nm were obtained after 72 h of magnetic stirring and heat treatment. These findings provide a new methodology for preparation of single-layer graphene oxide nanosheet colloids.
Volume 37 Issue 3 May 2014 pp 629-634
In this paper, the influence of temperature and voltage on direct electrochemical reduction were discussed in detail. Reduced graphene oxide is characterized with X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT–IR) and field emission scanning electron microscopy (FE–SEM). It is found that the reduction degree of graphene oxide (GO) decreases gradually with the increase of applied temperature. The optimal applied temperature found in our experiment is 20 °C; Meanwhile, as the applied voltage increases from 0.1 to 12.5 V, the reduction degree of graphene oxide increases gradually. However, above 2.5 V, increasing voltage has little effect on the reduction degree of graphene oxide.
Volume 37 Issue 6 October 2014 pp 1529-1533
The electrochemical reduction of graphene oxide typically involves complicated procedures, such as modification of electrodes and preparation of electrolytes, which is often needed in previous reports. In this paper, a simple and efficient electrochemical process is described for the synthesis of high-quality reduced graphene oxide. The main procedures involve the electrophoretic deposition of graphene oxide onto positive electrode and the subsequent in situ electrochemical negative reduction when the electrode changes from positive to negative. This approach opens up a new, practical and green reducing method to prepare largescale graphene.
Volume 38 Issue 1 February 2015 pp 7-12
The reduction of graphene oxide (GO) is a promising route to bulk produce graphene-based sheets. Different reduction processes result in reduced graphene oxide (RGO) with different properties. In this paper three reduction methods, chemical, thermal and electrochemical reduction, were compared on three aspects including morphology and structure, reduction degree and electrical conductivity by means of scanning electron microscopy (SEM), X-ray diffraction(XRD), the Fourier transform infrared spectroscopy (FT-IR) spectrum, X-ray photoelectron spectroscopy (XPS) and four-point probe conductivity measurement. Understanding the different characteristics of different RGO by preliminary comparison is helpful in tailoring the characteristics of graphene materials for diverse applications and developing a simple, green, and efficient method for the mass production of graphene.
Volume 42 | Issue 1