Articles written in Bulletin of Materials Science
Volume 15 Issue 2 April 1992 pp 161-170
Natural magnetite and hematite samples taken from iron ore deposits associated with Precambrian banded iron-formation (BIF) at Ari Dongri (20°23′N:81°3°E), Bastar district in Central India have been studied by Mossbauer, XRD and positron annihilation techniques. Three magnetite samples show a genetic association with α-Fe2O3 with a wide range of variations in Fe3O4:α-Fe2O3 ratio. The fourth sample, a typical specular hematite, shows α-Fe2O3 content of the order of 90%, the rest being magnetite. The magnetite present in the samples was found to be stoichiometric. None of the samples contains maghemite (γ-Fe2O3). Some geological implications of the observed variation in the oxidation states of the samples are considered.
Volume 19 Issue 6 December 1996 pp 1095-1103 Papers Presented At The Materials Science Section Of The 82nd Indian Science Congress, Calcutta, 1995
Five chromite samples procured from two different belts of India have been studied by57Fe Mössbauer spectroscopy. It is shown that four symmetric doublets are sufficient to fit the chromite spectrum; the Mössbauer parameters and the Fe3+/Fe2+ ratio are computed. For fully oxidized chromite with only Fe3+, two doublets are needed and the parameters are computed.
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