• D DAGDELEN

Articles written in Bulletin of Materials Science

• Synergistic effect of manganese and nitrogen codoping on photocatalytic properties of titania nanoparticles

Titanium dioxide is an n-type semiconductor widely used in applications like catalysts, optoelectonic materials, ceramics, H$_2$ generation, self-cleaning, water purification and solar cells. Sol–gel method has been chosen for nanoparticle synthesis because of its easy stoichiometry control, cost effectiveness and low temperature synthesis. In this study, titanium dioxide nanoparticles doped with different amounts of manganese (Mn) and nitrogen (N) were synthesized with sol–gel method. Crystal structure of undoped, Mn-doped, and Mn–N-codoped nanoparticles were determined with X-ray diffraction (XRD) analysis. Fourier transform infrared spectroscopy (FTIR) analysis was performed to identify the functional groups of nanoparticles. Photocatalytic analysis was carried out by methylene blue degredation under UV light for 1 h. X-rayphotoelectron spectroscopy (XPS) analysis was conducted to identify the chemical state and composition of the nanoparticles. Compared to the undoped TiO$_2$, which had 79.37% efficiency, Mn-doped and Mn–N-codoped TiO$_2$ nanoparticles have shown greater photocatalytic efficiency with 86.25 and 99.11% efficiencies, respectively. The results confirm that doping ofmanganese and nitrogen has affirmative effect on photocatalytic properties of synthesized nanoparticles.

• # Bulletin of Materials Science

Volume 43, 2020
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Continuous Article Publishing mode

• # Dr Shanti Swarup Bhatnagar for Science and Technology

Posted on October 12, 2020

Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020