• Bimal S Trivedi

      Articles written in Bulletin of Materials Science

    • Magnetic properties of the mixed spinel Co1+xSixFe2−2xO4

      S S Shinde K M Jadhav G K Bichile Bimal S Trivedi R G Kulkarni

      More Details Abstract Fulltext PDF

      The structural and magnetic properties of the mixed spinel Co1+xSixFe2−2xO4 system for 0·1≤x≤0·6 have been studied by means of X-ray diffraction, magnetization, and Mössbauer spectroscopy measurements. X-ray intensity calculations indicate that Si4+ ions occupy only tetrahedral (A) sites replacing Fe3+ ions, and the added Co2+ ions substitute for (B) site Fe3+ ions. The Mössbauer spectra at 300 K have been fitted with two sextets in the ferrimagnetic state corresponding to Fe3+ at the A and B sites, forx≤0·3. The Mössbauer intensity data shows that Si possesses a preference for the A site of the spinel. The variation of the saturation magnetic moment per formula unit measured at 300 K with the Si content, is explained on the basis of Neel’s collinear spin ordering model forx≤0·3 which is supported by Mössbauer, and X-ray data. The Curie temperature decreases nearly linearly with increase of the Si content, forx=0·1–0·6.

  • Bulletin of Materials Science | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2017-2019 Indian Academy of Sciences, Bengaluru.