Articles written in Bulletin of Materials Science
Volume 6 Issue 3 July 1984 pp 603-609
Rare earth trialuminides (RAl3) exhibit an interesting series of structures changing from 2H to 3C in the bulk form. Many of the rare earth trialuminides have been recently found to exhibit curious structural characteristics such as the occurrence of the modulated phases. A detailed investigation of the formation synthesis and characterization of some binary and ternary alloys of the rare earth-aluminium system has been carried out. High resolution microscopic technique has been employed to study the modulated phases for some alloys
Volume 15 Issue 3 June 1992 pp 191-199
Proton transport in potassium dihydrogen phosphate (KDP) and ammonium dihydrogen phosphate (ADP) is briefly reviewed. The experimental results of Wagner’s polarization measurement, coulometry, infrared spectroscopy, transient ionic current measurement, the variation of electrical conductivity with temperature and electrogravimetric analysis for KDP and ADP are reported. H+ and OH- ions are ascertained as the mobile ionic species. A new mechanism for the proton transport in KDP and ADP is suggested: A three-fold rotation of H2P4- units about any of the axes of PO4 tetrahedra leads to a configuration like O...H...H...O, the rearrangement of which provides H...O...H bridge that gets electrodissociated on the application of a d.c. electric field.
Volume 31 Issue 3 June 2008 pp 233-240
In the present study, a novel method involving nitrogen plasma annealing has been reported for preparing InN nanoparticle/nanorod structures and for improving the properties of InN nanoparticle layers. Plasma annealed structures have been characterized by X-ray diffraction, atomic force microscopy and photoluminescence spectroscopy techniques. InN nanoparticle layers have been prepared using activated reactive evaporation set up. It has been observed that there is a remarkable improvement in the conductivity and crystallinity of InN nanoparticle layers on annealing in nitrogen plasma. This has been attributed to the increase in the nitrogen content of the samples. Experiments involving plasma annealing of In nanorods deposited oxide template has also been carried out. It was found that on plasma treatment In nanorods get converted to mixed phase InN nanorods with hexagonal and cubic fractions.
Volume 31 Issue 4 August 2008 pp 655-664 Composites
In the present study, microwave energy (2.45 GHz) has been used to prepare nickel oxide–yttria stabilized zirconia (NiO–YSZ) composites of composition, 𝑚NiO–(1 – 𝑚) Zr0.9Y0.1O1.95 (𝑚 = 0.2, 0.3, 0.4, 0.5 and 0.6), from a precursor obtained by mixing NiO, Y2O3 and monoclinic ZrO2 in their stoichiometric ratio. The composites have been prepared by conventional processing also to compare the products with those of microwave processed products. During comparison, it was observed that NiO–YSZ composites of each composition obtained by microwave processing had cubic phase of YSZ while in the conventionally prepared composites of compositions, 𝑚 = 0.2 and 0.3, monoclinic, tetragonal and cubic phases of zirconia existed instead of its pure cubic phase. The composites were reduced to yield Ni–YSZ.
Volume 38 Issue 6 October 2015 pp 1533-1538
In recent years the application of metal nanoparticles is gaining attention in various fields. The present study focuses on the additive effect of `green’ synthesized iron nanoparticles (FeNPs) on dark fermentative hydrogen (H2) production by a mesophilic soil bacterium
Volume 42 | Issue 3