• ANTONIO LICCIULLI

      Articles written in Bulletin of Materials Science

    • Diatomite/silver phosphate composite for efficient degradation of organic dyes under solar radiation

      SANOSH KUNJALUKKAL PADMANABHAN SUDIPTO PAL ANTONIO LICCIULLI

      More Details Abstract Fulltext PDF

      In this study, an effort has been made to synthesize diatomite/silver phosphate (DT/AgP) composites and dye degradation test was carried out to evaluate the photocatalytic activity under solar light irradiation. Diatomite–silverphosphate composites with different DT/AgP ratios were prepared by precipitation of Ag$_3$PO$_4$ on diatomite that led to the formation of small Ag$_3$PO$_4$ particles on the diatomite surfaces. UV–visible diffuse reflectance analysis shows that DT/AgP composites can absorb visible wavelength, whereas TiO$_2$ catalyst only work under UV irradiance. Compared to pure AgP, the composite samples show higher specific surface area measured by Brunauer–Emmett–Teller analysis. Dye degradation test under solar light irradiation reveals that the photocatalytic reaction follows a pseudo-first-order rate law and the composite catalyst with DT/AgP ratio 1:0.8 shows better catalytic activity towards both rhodamine B and methyl orange degradation. As reference, a well-known commercial TiO$_2$ (Evonik-P25) was used in dye degradation test. It could be presumed that deposition of silver phosphate clusters (Ag$_3$PO$_4$, AgP) on diatom frustules (diatomite) provided anefficient photocatalyst activated by solar light irradiation.

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