• Issue front cover thumbnail

      Volume 71, Issue 5

      November 2008,   pages  886f-1207

    • Foreword

      V C Sahni

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    • Preface

      R Mukhopadhyay S L Chaplot

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    • The spallation neutron source: New opportunities

      Ian S Anderson

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      The spallation neutron source (SNS) facility became operational in the spring of 2006, and is now well on its way to become the world-leading facility for neutron scattering. Furthermore, the SNS and the HFIR reactor facility, newly outfitted with a brilliant cold source and guide hall, were brought together within a single Neutron Sciences Directorate at ORNL providing the opportunity to develop science and instrumentation programs which take advantage of the unique characteristics of each source. SNS and HFIR will both operate as scientific user facilities. Access to these facilities is being managed under an integrated proposal system, which also includes the Center for Nanophase Materials Sciences (CNMS) and the electron microscopes in the Shared Research Equipment (SHARE) program.

      Presently, SNS has three instruments operating in the user program and seven more will begin operations in 2008. When complete, the facility will accommodate 25 instruments enabling researchers from the United States and abroad to study materials science that forms the basis for new technologies in telecommunications, manufacturing, transportation, information technology, biotechnology, and health.

    • Scientific horizons at the Institut Laue-Langevin

      Richard Wagner

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      In order to maintain the scientific value of the ILL and to respond to the changing needs of its broad user community throughout Europe and beyond, in 2001 the Millennium Programme (Phase M-0, 2001–2008) was launched to boost the quality of ILL's experimental facilities. The ongoing renewal programme has been directed to-wards renewing some of the neutron delivery systems – neutron guides and beam tubes – towards improvement of sample environment and installation of user-friendly data acquisition/handling systems, and in particular towards upgrading neutron instrumentation.

      Already at this stage, the upgrading of eleven instruments and some neutron delivery systems has increased the overall efficiency (expressed in terms of count rates) of ILL's instruments suite by more than a factor of 14. This does not only render the time for a neutron scattering experiment much shorter but, in particular, does open access to new scientific challenges such as in nanoscience and biology where often only small samples are available.

      In the recently launched Phase M-1 (2007–2013), five new instruments as well as new neutron guide systems will be built with the emphasis on neutron diffraction and spectroscopy with cold neutrons. This will further boost the application of neutron scattering techniques to materials science problems and to condensed matter research, and will keep the institute at the forefront of neutron science well beyond 2020.

    • ISIS Facility – Past achievements and future prospects

      Uschi Steigenberger

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      The current status of the ISIS Pulsed Neutron and Muon Facility will be described covering operations and developments. Construction of a second target station was approved in 2004 including funding for the first seven neutron scattering instruments. Progress with the second target station project will be reviewed and updates on the design status of the seven `Day One' instruments, as well as plans for the next phase of the instrumentation will be presented.

    • Towards the construction of the European spallation source – The Scandinavian experience

      C J Carlile C Vettier P Carlsson

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      The possible realization of the European spallation source has been a long and winding story. However, thanks to the conjunction of a number of events it now looks highly probable that in 2008 there will indeed be a decision on the site and on a funding partnership of European countries who will together build and operate this long-pulse spallation neutron source. Currently there is a reference design comprising of a 632 m long proton accelerator which will deliver 2 ms pulses of protons to a liquid metal target with 22 instruments receiving thermal and cold neutron beams and providing unprecedented data rates.

      Lund is one of the two consortia competing to build the ESS – the ESS Scandinavia and a Hungarian–Spanish collaboration which is currently deciding on its preferred site. The Lund experience is one which highlights the many delicate steps which must be taken in order to get close to such decisions in a Europe of 30 plus nations. Of particular interest is the Energy Management Strategy which ESS Scandinavia would implement if Lund were to be the eventual chosen site. This will be set into the context of the political iniatives to mitigate the effects of global warming.

    • Advances in neutron tomography

      W Treimer

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      In the last decade neutron radiography (NR) and tomography (NCT) have experienced a number of improvements, due to the well-known properties of neutrons interacting with matter, i.e. the low attenuation by many materials, the strong attenuation by hydrogenous constituent in samples, the wavelength-dependent attenuation in the neighbourhood of Bragg edges and due to better 2D neutron detectors. So NR and NCT were improved by sophisticated techniques that are based on the attenuation of neutrons or on phase changes of the associated neutron waves if they pass through structured materials.

      Up to now the interaction of the neutron spin with magnetic fields in samples has not been applied to imaging techniques despite the fact that it was proposed many years ago. About ten years ago neutron depolarization as imaging signal for neutron radiography or tomography was demonstrated and in principle it works. Now one can present much improved test experiments using polarized neutrons for radiographic imaging. For this purpose the CONRAD instrument of the HMI was equipped with polarizing and analysing benders very similar to conventional scattering experiments using polarized neutrons. Magnetic fields in different coils and in samples (superconductors) at low temperatures could be visualized. In this lecture a summary about standard signals (attenuation) and the more `sophisticated' imaging signals as refraction, small angle scattering and polarized neutrons will be given.

    • Dynamical scaling laws – A few unanswered questions

      S Mazumder

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      When a system with continuous symmetry is quenched instantly to a broken symmetry state, topological defects appear in an otherwise homogeneous medium of continuous symmetry. Further growth of the topological defects are of continuous nature such that the time evolution of the system can be described by Ginzburg–Landau free energy functionals.

      The phenomenon of new phase formation is a representative example of first-order transition. The phenomenon is fundamental and of immense interest as an example of a highly nonlinear process far from equilibrium. The second phase grows with time and in later stages all domain sizes are much larger than all microscopic lengths. In the large time limit, the new phase-forming systems exhibit self-similar growth pattern with dilation symmetry, with time-dependent scale, and scaling phenomenon. The phenomenon is indicative of the emergence of a morphological pattern of the domains at earlier times looking statistically similar to a pattern at later times apart from the global change of scale implied by the growth of time-dependent characteristic length scale $L(t)$ – a measure of the time-dependent domain size of the new phase.

      The scaling hypothesis assumes the existence of a single characteristic length scale $L(t)$ such that the domain sizes and their spatial correlation are time invariant when the lengths are scaled by $L(t)$. Quantitatively, for isotropic systems, the equal-time spatio-temporal composition modulation autocorrelation function $g(r, t)$, which reflects the way in which the mean density of the medium varies as a function of distance from a given point, should exhibit the scaling form with time-dependent dilation symmetry $g(r, t) = f (r/L(t))$.

      The scaling function $f (r/L(t))$ is universal in the sense that it is independent of initial conditions and also interactions as long as they are short ranged. However, form of $f (r/L(t))$ depends non-trivially on 𝑛, the number of components in the vector order- parameter field exhibiting the scaling behaviour, and 𝑑, the dimensionality of the system. It is important to note that the scaling hypothesis has not been proved conclusively except for some model systems.

      The Fourier transform of $g(r, t)$, the structure factor or scattering function $S(q, t)$ for a 𝑑 dimensional Euclidean system, obeys simple scaling ansatz at later times, $S(q, t) = L(t) ^{d} F (qL(t))$.

      Based on some of our recent observations on phase separation of a multicomponent alloy involving hydration of cementitious material, it is proposed to discuss some unanswered questions pertinent to the validity of dynamical scaling laws addressing some issues like (i) uniqueness of characteristic length $L(t)$, (ii) the extent of validity of the scaling laws for new phase formation in the case of non-Euclidean fractal systems, (iii) the extent of validity of the scaling laws for multicomponent systems.

      The need for investigations examining the extent and the nature of the validity of the scaling laws for confined systems and for systems subjected to random field will also be discussed.

    • Perspectives of extreme sample environment in neutron scattering and consequences for instrumentation

      Michael Steiner

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      Because neutrons can penetrate bulky pieces of matter, increasingly complex sample environment is requested by the users of neutron beams. This corresponds to the ever-growing complexity of the scientific problems addressed by neutron scatterers. Until now such requirements could be satisfied by sample environment, which could be added to the instruments without major modifications. Now it becomes evident, that for certain applications further progress is possible only by bringing the neutrons to the sample environment instead of bringing the sample environment to the neutrons. As one of the first examples of this concept we will discuss the high field magnet (HFM), which Hahn-Meitner-Institute Berlin (HMI) and the National High Magnetic Field Laboratory Tallahassy (NHFML) are constructing jointly for BENSC at HMI. At BENSC the HMI has built in the meantime a dedicated instrument based on the TOF principle to be equipped with the HFM to enable experiments at fields up to 25 T.

    • Progress with OPAL, the new Australian research reactor

      R A Robinson

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      Australian science is entering a new `golden age', with the start-up of bright new neutron and photon sources in Sydney and Melbourne, in 2006 and 2007 respectively. The OPAL reactor and the Australian Synchrotron can be considered as the greatest single investment in scientific infrastructure in Australia's history. They will essentially be `sister' facilities, with a common open user ethos, and a vision to play a major role in international science. Fuel was loaded into the reactor in August 2006, and full power was (20 MW) achieved in November 2006. The first call for proposals was made in 2007, and commissioning experiments have taken place well before then. The first three instruments in operation are high-resolution powder diffractometer (for materials discovery), high-intensity powder diffractometer (for kinetics experiments and small samples) and a strain scanner (for mechanical engineering and industrial applications). These are closely followed by four more instruments with broad application in nanoscience, condensed matter physics and other scientific disciplines. Instrument performance will be competitive with the best research-reactor facilities anywhere. To date there is committed funding for nine instruments, with a capacity to install a total of $\sim 18$ beamlines. An update will be given on the status of OPAL, its thermal and cold neutron sources, its instruments and the first results.

    • A deeper look into magnetic nanostructures using advanced scattering methods

      T H Brückel E Kentzinger S Mattauch A Paul U Rücker J Voigt

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      Magnetic thin film systems and laterally patterned magnetic media are the basis of spintronic devices for information technology. In this contribution, we will show that neutron scattering under grazing incidence with polarization analysis is able to provide unique depth resolved information on magnetization, magnetic correlations and magne-tization dynamics relevant for basic and applied research on nanostructured magnetic materials.

      It is well established that specular neutron reflectivity with polarization analysis from thin film systems and multilayers provides layer-resolved information on interface rough-ness and on the laterally averaged magnetization. Off-specular diffuse scattering with polarization analysis gives access to lateral correlations, i.e. the detailed interface morphology, the magnetic order of nanoscale objects (stripes or islands), the magnetic fluctuations or domain structure. Depending on the scattering geometry – reflectometry or grazing incidence small angle neutron scattering (GISANS) – correlations on lateral length scales from the nanometer up to the 100 micrometer range become accessible. Close to total reflection, kinematical scattering theory breaks down and dynamical effects have to be taken into account. Simulations in the distorted wave Born approximation (DWBA) allow one to extract quantitative parameters for a statistical model description.

      On several examples we will demonstrate the power of the method – from the magnetic fluctuations in remanent sputtered films via the magnetic structure of rare earth multilayers with competing interactions to the remagnetization process of exchange bias systems or the domain structures of laterally patterned giant magnetoresistance multilayers. Finally we will give an outlook on what will be possible on next generation instruments such as the magnetism reflectometer MARIA of the Juelich Centre for Neutron Science (JCNS) at FRM-II.

    • Magnetizing and heating quantum spin ladders

      Andrey Zheludev

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      Quasi-one-dimensional quantum spin liquids, such as weakly coupled even-legged S=1/2 spin ladders or spin tubes, have a singlet non-magnetic ground state and gap in the excitation spectrum. Their low-temperature properties can be described in terms of triplet massive quasiparticles. These magnons possess some unique features due to the peculiar topology of one dimension. For example, two-particle interactions totally destroy single-particle states for certain energy and momentum transfers, resulting in the so-called termination of the magnon spectrum. At high field a Bose–Einstein condensation of these magnons produces a `quantum spin solid' phase, where `conventional` antiferromagnetic order coexists with excitations that are totally outside conventional spin wave theory. At finite temperatures strong repulsion between quasiparticles leads to a universal renormalization of their masses and lifetimes. These diverse phenomena are best probed by neutron scattering experiments that directly measure the spin correlation functions and excitation spectra.

    • Opportunities for in-situ diffraction studies of advanced materials under extreme conditions at the US spallation neutron source

      J P Hodges

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      The spallation neutron source (SNS) is an accelerator-based neutron source in Oak Ridge, Tennessee. Currently ramping up to 1.4 MW operating power, SNS will provide the most intense pulsed neutron beams in the world for scientific research and industrial development. Built by a partnership of six DOE laboratories SNS is operated as a user facility, open to scientists and engineers from universities, industry, and government laboratories in the United States and abroad. Eighteen dedicated beamline instruments are currently funded; four are completed and in operation, five are to be commissioned within a year and the others are at various stages of design and construction. All instruments at SNS have been designed to best in class and will provide unprecedented opportunities to explore the structure and dynamics of all materials. Amongst the funded instruments are a high-resolution very fast powder diffractometer (POWGEN3) optimized for parametric studies of materials under a wide range of conditions (𝑇, 𝑃, 𝐻 and flowing gases), an ultrahigh-pressure diffractometer (SNAP) for materials under extreme conditions of pressure (up to 100 GPa) and temperature, an engineering materials diffractometer (VULCAN) for mapping strain, texture and fundamental aspects of materials behaviour of high performance materials under strain forces, a high flux disordered materials diffractometer (NOMAD) for liquids, glasses and disorder in crystalline materials, and a small angle scattering diffractometer (EQSANS) for investigating precipitates, crystallization, domains and nanoparticles in composite materials. ORNL/SNS is managed by UT-Battelle, LLC, for the U.S. Department of Energy under contract DE-AC05-00OR22725.

    • Dynamic instability at the origin of oxygen ion conduction in solid oxides at ambient temperature

      Helmut Schober Werner Paulus Tanguy Berthier Olivier Hernandez Monica Ceretti Stefan Eibl Mark Johnson Marie Plazanet Carlo Lamberti

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      The conduction of ions in solids is of paramount importance for many technological devices like solid oxide fuel cells. It is inherent to solids that ions are trapped within potential wells. Their transport thus has to be activated at the price of elevated temperatures, a condition that is often incompatible with technological applications. While atomic vibrations have the potential of assisting the diffusion process, little is known about the exact conditions that have to be reunited to trigger such a process. Here we show that dynamic instability is responsible for the large ion conduction in SrFeO2.5 with brownmillerite-type structure. Using ab-initio molecular dynamics calculations we observe the migration of oxygen ions away from the original lattice positions into the vacancy channels of the brownmillerite structure. The escape of the oxygen ion is rendered possible by the destabilization of a shallow potential well due to low-lying vibrational modes, the existence of which is confirmed by neutron spectroscopy. Analysing the lattice dynamics as a function of structural parameters it is possible to identify the structural subtleties responsible for the instability. It is found that in the isostructural compound CaFeO2.5, fast oxygen ion diffusion is absent at low temperatures. The origin of this behaviour lies with the slightly different iron–oxygen distances rendering the potentials better defined and less amenable to dynamical destabilization. The here-introduced concept of dynamical instability is not restricted to the discussed class of materials but may be applied to any system that features ion conduction at low temperatures.

    • Intermolecular hydrogen bonds: From temperature-driven proton transfer in molecular crystals to denaturation of DNA

      Mark Johnson

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      We have combined neutron scattering and a range of numerical simulations to study hydrogen bonds in condensed matter. Two examples from a recent thesis will be presented. The first concerns proton transfer with increasing temperature in short inter-molecular hydrogen bonds [1,2]. These bonds have unique physical and chemical properties and are thought to play a fundamental role in processes like enzymatic catalysis. By combining elastic and inelastic neutron scattering results with ab initio, lattice dynamics and molecular dynamics simulations, low frequency lattice modes are identified which modulate the potential energy surface of the hydrogen bond proton and drive proton transfer.

      The second example concerns base-pair opening in DNA which is the fundamental physical process underlying biological processes like denaturation and transcription. We have used an emprical force field and a large scale, all-atom phonon calculation to gain insight into the base-pair opening modes and the apparent `energy gap' between the accepted frequencies for these modes ($\sim 100$ cm-1 or $\sim 140$ K) and the temperature of the biological processes (room temperature to 100° C) [3]. Inelastic neutron scattering spectra on aligned, highly crystalline DNA samples, produced at the ILL, provide the reference data for evaluating the precision of these simulation results.

    • Structure of polymer chains under confinement

      Jyotsana Lal

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      We observe by SANS the structure of neutral polystyrene and charged polystyrene sulphonate chains in semi-dilute solutions confined in a model nanoporous glass, Vycor. The size of the free chains in solution is always larger than the pore diameter, 70. The use of a suitable mixture of hydrogenated and deuterated solvents and polymers enables us to measure directly the form factor of one single chain among the others. Single chain form factor was observed both for bulk and confined chains using the condition of zero average contrast. Our measurements on neutral polymer chains are in agreement with the theoretical predictions established by Daoud and de Gennes for chains confined in a cylindrical pore when the chains are entangled and laterally squeezed but remain ideal at large scale along the cylinder axis because of the screening of the excluded volume interactions (so-called regime of ``semi-dilute cigars"). For confined charged polymers, a peak is observed whose intensity increases with molecular weight and the asymptotic $1/q$ scattering region is extended compared to the bulk. We infer that the chains are sufficiently extended, under the influence of confinement, to highlight the large scale disordered structure of Vycor even under contrast matched conditions. The asymptotic behaviour of the observed interchain structure factor is $\approx 1/q^{2}$ and $\approx 1/q$ for free and confined chains respectively.

    • Generalized approach to non-exponential relaxation

      R M Pickup R Cywinski C Pappas P Fouquet B Farago P Falus

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      Non-exponential relaxation is a universal feature of systems as diverse as glasses, spin glasses, earthquakes, financial markets and the universe. Complex relaxation results from hierarchically constrained dynamics with the strength of the constraints being directly related to the form of the relaxation, which changes from a simple exponential to a stretched exponential and a power law by increasing the constraints in the system. A global and unified approach to non-exponentiality was first achieved by Weron and was further generalized by Brouers and Sotolongo-Costa, who applied the concept of non-extensive entropy introduced by Tsallis to the relaxation of disordered systems.

      These concepts are now confronted with experimental results on the classical metallic spin glasses CuMn, AuFe and the insulating system EuSrS. The revisited data have also be complemented by new results on several compositions of the classical CuMn spin glass and on systems, like CoGa and CuCo, the magnetic behaviour of which is believed to arise from magnetic clusters and should be characteristic for superparamagnetism.

    • Changes in the excitations related to the superconducting transition in V3Si

      M Yethiraj

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      In earlier studies of phonons in V3Si, a gradual softening of the $(h h 0)$ branch was observed and attributed to the martensitic transition in this compound, which precedes the onset of superconductivity by a few degrees K. In this work, the temperature dependence of the transverse acoustic branch along the $h h 0$ direction was studied in greater detail and it is shown that while the TA $h h 0$ mode starts to soften at relatively high temperatures (> 200 K), an anomalous inelastic peak, which is somewhat localized in q, occurs just below $T_{\text{c}}$. The intensity of this mode correlates extremely well with the onset of the superconducting phase and varies as the order parameter with temperature and applied field. The similarities in the phonon softening and Fermi surface anisotropy between this compound and the rare-earth nickel borocarbides suggests the existence of a common mechanism for the superconducting transition.

    • Stability of ordered phases in block copolymer melts and solutions

      Kell Mortensen

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      Block copolymer melts and solutions assemble into nanosized objects that order into a variety of phases, depending on molecular parameters and mutual interactions. Beyond the classical phases of lamella ordered sheets, hexagonally ordered cylinders and cubic ordered spheres, the complex bicontinuous gyroid phase and the modulated lamellar phase are observed near the phase boundaries. The stability of these phases has been discussed on the basis of theoretical calculations. Here, we will discuss new experimental results showing that the given ordered phase depends critically on both molecular purity and mechanical treatment of the sample. While a variety of block copolymer micellar systems have been shown to undergo the liquid-to-bcc-to-fcc phase sequence upon varying micellar parameters (or temperature), we find for a purified system a different sequence, namely liquid-to-fcc-to-bcc [1]. The latter sequence is by the way the one predicted for pure block copolymer melts. External fields like shear or stress may also affect the ordered phase. Applying well-controlled large-amplitude oscillatory shear can be used to effectively control the texture of soft materials in the ordered states. As an example, we present results on a body-centred-cubic phase of a block copolymer system, showing how a given texture can be controlled with the application of specific shear rate and shear amplitude $[2,3]$. Shear may however also affect the thermodynamic ground state, causing shear-induced ordering and disordering (melting), and shear-induced order–order transitions. We will present data showing that the gyroid state of diblock copolymer melts is unstable when exposed to large amplitude/frequency shear, transforming into the hexagonal cylinder phase [4]. The transformation is completely reversible. With the rather slow kinetics in the transformation of copolymer systems, it is possible in detail to follow the complex transformation process, where we find transient ordered structures [5].

    • Constraint and flow: Poiseuille shear response of a surfactant sponge phase

      W A Hamilton L Porcar G G Warr P D Butler

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      To minimize their free energy in aqueous solution, surfactant molecules self-assemble to form some basic morphologies – globular micelles, highly extended theadlike micelles and membrane bilayers – which themselves order to display a rich variety of mesophase symmetries and properties. In membrane systems one of the more striking distinctions is that between the free flowing L3 `sponge' phase and the adjacent highly birefringent viscous L$_{\alpha}$ phase. Their different macroscopic properties reflect their mesophase membrane ordering – highly anisotropic stacking in the L$_{\alpha}$ phase, and an isotropic labyrinth of interconnecting passages in L3 sponges spanning solution space, but without long range order. Our group has spent a number of years investigating the shear flow responses of L3 phases as well as their accommodation to the constraint of a proximate surface – in both these situations over appropriate ranges the higher symmetry of the stacked membrane phases is established. These phases exhibit a strong dynamical scaling due to their entropic stabilization by hydrodynamic fluctuations, and a narrowing of this fluctuation spectrum in the proximity of a solid surface must also to some extent frustrate these membranes dynamically as well as geometrically. In recent experiments, we have begun measurements of the Poiseuille surface shear response of sponge phases a situation in which one might expect effects from an interplay between these dynamic and geometric effects.

    • Thiourea-doped ammonium dihydrogen phosphate: A single crystal neutron diffraction investigation

      A Jayarama M R Suresh Kumar S M Dharmaprakash R Chitra R R Choudhury

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      Thiourea-doped ammonium dihydrogen phosphate (TADP) exhibits nonlinear optical property and the second harmonic generation efficiency of these crystals is three times that of pure ammonium dihydrogen phosphate (ADP) crystal. In this context, the study of structural distortion in the thiourea-doped ADP crystal is significant, hence single neutron diffraction investigations were undertaken. The final 𝑅-factors are: $R[F^{2} > 2\sigma(F^{2})] = 0.11$, Goodness of fit $(S) = 1.15$. Though the dopant could not be located from the difference Fourier map, the cell parameters ($a = b = 7.531(3)$ Å, $c = 7.544(5)$ Å) were found to be significantly greater than that of pure ADP at RT ($a = b = 7.502(1)$ ̊Å, $c = 7.546(1)$ ̊Å). This indicates that the dopant concentration in the crystals is small but enough to bring changes in the overall average structure.

    • Single crystal neutron diffraction study of triglycine sulphate revisited

      Rajul Ranjan Choudhury R Chitra

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      In order to get the exact hydrogen-bonding scheme in triglycine sulphate (TGS), which is an important hydrogen bonded ferroelectric, a single crystal neutron diffraction study was undertaken. The structure was refined to an 𝑅-factor of $R[F^{2}] = 0.034$. Earlier neutron structure of TGS was reported with a very limited data set and large standard deviations. The differences between the present and the earlier reported neutron structure of TGS are discussed.

    • Structural and magnetic properties of the layered compound Ca2.375La0.125Sr0.5GaMn2O8

      A K Bera S M Yusuf A Jain

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      The brownmillerite-type layered compound Ca2.375La0.125Sr0.5GaMn2O8 has been synthesized. The crystal and magnetic structures have been refined by the Rietveld analysis of the neutron powder diffraction patterns at 300 and 20 K. This compound crystallizes in the orthorhombic symmetry under the space group Pcm21 ($a = 5.447(2)$, $b = 11.359(4)$ and $c = 5.322(2)$ Å). The compound is found to be antiferromagnetic at 20 K. The ordered Mn magnetic moment, aligned along the crystallographic 𝑏-direction, is derived to be $2.53(5) \mu_{B}$ per Mn ion at 20 K.

    • Neutron diffraction study of quasi-one-dimensional spin-chain compounds Ca3Co$_{2−x}$Fe$_{x}$O6

      Anil Jain S M Yusuf Sher Singh

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      We report the results of the DC magnetization, neutron powder diffraction and neutron depolarization studies on the spin-chain compounds Ca3Co$_{2−x}$Fe$_{x}$O6 ($x = 0$, 0.1, 0.2 and 0.4). Rietveld refinement of neutron powder diffraction patterns at room temperature confirms the single-phase formation for all the compounds in rhombohedral structure with space group R$\bar{3}$c. Rietveld refinement also confirms that Fe was doped at the trigonal prism site, 6a (0, 0, 1/4) of Co. The high temperature magnetic susceptibility obeys the Curie–Weiss law; the value of the paramagnetic Curie temperature ($\theta_{p}$) decreases as the concentration of iron increases and it becomes negative for $x = 0.4$. No extra Bragg peak as well as no observable enhancement in the intensity of the fundamental (nuclear) Bragg peaks has been observed in the neutron diffraction patterns down to 30 K. No depolarization of neutron beam has been observed down to 3 K confirming the absence of ferro- or ferrimagnetic-like correlation.

    • Structural behaviour of AgNO3 at low temperatures by neutron diffraction

      P U Sastry P S R Krishna Lata Panicker A B Shinde

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      Structural behaviour of silver nitrate (AgNO3) at low temperatures has been investigated by neutron powder diffraction and differential scanning calorimetry (DSC). Analysis showed abnormal changes in the rotations of nitrate (NO3) anions and thermal displacement parameters of the atoms near 220 K and 125 K. However, the basic lattice is compatible with the orthorhombic symmetry (space group Pbca) till 12 K. The fine, small-scale structural anomalies probably originate from freezing of reorientation of NO3 ions from high-temperature disordered phase.

    • Cation disorder and structural studies on Bi$_{4−x}$Nd$_{x}$Ti3O12 $(0.0 \leq x \leq 2.0)$

      S N Achary S J Patwe P S R Krishna A B Shinde A K Tyagi

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      Here we report the results of combined powder X-ray and neutron diffraction studies of Bi$_{4−x}$Nd$_{x}$Ti3O12 $(0.0 \leq x \leq 2.0)$ compositions. The parent Bi4Ti3O12 has an orthorhombic lattice (space group: B2cb) with unit cell parameters $a$ = 5.4432(5) Å, $b$ = 5.4099(5) Å and $c$ = 32.821(2) Å, and $V$ = 966.5(1) Å3. This orthorhombic lattice is retained in all the studied compositions. The unit cell parameters gradually decrease with Nd 3+ ion concentration with a discontinuity at $x = 0.75$. Orthorhombicity of the lattice decreases with increase in Nd3+ content in the lattice. The orthorhombic unit cell parameters for a representative Bi2Nd2Ti3O12 composition are: $a$ = 5.3834(9), $b$ = 5.3846(9) and $c$ = 32.784(1) Å. The observed orthorhombic distortion at $x$ = 2.0 is very small and thus the crystal structure apparently has a pseudo-tetragonal lattice. In addition, Nd3+ preferentially substitutes in the perovskite slab of the Aurivillius structure. The fraction of Nd3+ in the fluorite slab increases with increase in Nd3+ contents.

    • Neutron diffraction studies on Ca$_{1-x}$Ba$_{x}$Zr4P6O24 solid solutions

      S N Achary O D Jayakumar S J Patwe A B Shinde P S R Krishna S K Kulshreshtha A K Tyagi

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      Herein we report the results of detailed crystallographic studies of Ca$-[1-x}$Ba$_{x}$Zr4P6O24 compositions from combined Rietveld refinements of powder X-ray and neutron diffraction data. All the studied compositions crystallize in rhombohedral lattice (space group R-3 No. 148). A continuous solid solution is concluded from the systematic variation of unit cell parameters. The variation of unit cell parameters with the composition indicates decreasing trend in 𝑎 parameter with increasing Ba2+ concentration contrast to an increasing trend in 𝑐 parameter.

    • Probing polymer nanocomposite morphology by small angle neutron scattering

      Puyam S Singh Vinod K Aswal

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      Polyamide nanocomposite films were prepared from nanometer-sized silica particles having particle radius of gyration ($R_{\text{g}$) of about 66 Å and trimesoyl chloride-𝑚-phenylene diamine-based polyamides having macromolecular units of about 100-140 Å. The nanoscale morphology of the samples was characterized using small angle neutron scattering (SANS). SANS reveals that silica nanoparticles interact well with the polyamide units only at limited silica loading.

    • Small angle neutron scattering studies of mixed micelles of sodium cumene sulphonate with cetyl trimethylammonium bromide and sodium dodecyl sulphate

      K V Padalkar V G Gaikar V K Aswal

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      The aqueous solutions of sodium cumene sulphonate (NaCS) and its mixtures with each of cetyl trimethylammonium bromide (CTAB) and sodium dodecyl sulphate (SDS) are characterized by small angle neutron scattering (SANS). NaCS when added to CTAB solution leads to the formation of long rod-shaped micelles with a dramatic increase in the CTAB aggregation number. Its addition to SDS on the other hand results in the formation of smaller mixed micelles where part of SDS molecules in the micelle is replaced by NaCS molecules.

    • Effects of sintering on microstructure and dielectric response in YCrO3 nanoceramic

      J Bahadur D Sen S Mazumder V K Aswal V Bedekar R Shukla A K Tyagi

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      Effects of sintering on pore morphology and dielectric response have been investigated. Pore structure has been probed by small angle neutron scattering (SANS). It has been observed that the size distribution becomes less polydisperse with a slight modification in the distribution as sintering temperature is increased. Dielectric response in the frequency range 0.02–1000 kHz is significantly altered by modification of pore structure because of sintering. A transition from non-Debye type to near-Debye type response has been observed as the sintering temperature is increased.

    • Effect of heat treatment on pore structure in nanocrystalline NiO: A small angle neutron scattering study

      J Bahadur D Sen S Mazumder S Ramanathan

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      Nanocrystalline nickel oxide powders were calcined at 300, 600 and 900°C and pore structure evolution was followed by small angle neutron scattering (SANS). Pore size distributions at two widely separated size ranges have been revealed. Shrinkage of larger-sized pore with reduction in polydispersity has been observed with increasing heat treatment temperature. The pore structures at various heat treatment temperatures do not scale. This has been attributed to the grain boundary diffusion leading to an asymmetric shrinkage of the pores.

    • Morphology of carbon nanotubes prepared via chemical vapour deposition technique using acetylene: A small angle neutron scattering investigation

      D Sen K Dasgupta J Bahadur S Mazumder D Sathiyamoorthy

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      Small angle neutron scattering (SANS) has been utilized to study the morphology of the multi-walled carbon nanotubes prepared by chemical vapour deposition of acetylene. The effects of various synthesis parameters like temperature, catalyst concentration and catalyst support on the size distribution of the nanotubes are investigated. Distribution of nanotube radii in two length scales has been observed. The number density of the smaller diameter tubes was found more in number compared to the bigger one for all the cases studied. No prominent scaling of the structure factor was observed for the different synthesis conditions.

    • Investigation on pore structure and small-scale agglomeration behaviour in liquid phase sintered SiC using small angle neutron scattering

      D Sen J Bahadur S Mazumder T Mahata M Syambabu P K Sinha

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      Mesoscopic density fluctuations in liquid phase sintered silicon carbide have been investigated using small angle neutron scattering (SANS). The increase in the additives results in the modification in the pore size distribution and to some extent the total porosity. SANS revealed a mass fractal nature of the agglomerated matrix microstructure. The fractal dimension of the matrix does not change appreciably with the additives although the upper cut-off value of the fractal decreases significantly with the increase in the additives. The liquid phase sintering due to the presence of additives helps to achieve higher level of densification. However, the agglomeration hinders achievement of the fully dense pellets.

    • Small angle neutron scattering study of U(VI) third phase formation in HNO3/DHDECMP–𝑛-dodecane system

      K V Lohithakshan V K Aswal S K Aggarwal

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      Small angle neutron scattering studies (SANS) were carried out to understand the formation of third phase in DHDECMP–dodecane–UO2(NO3)2/HNO3 system. It was observed that third phase formation takes place due to the formation of UO2(NO3)2. DHDECMP reverse micelles in the dodecane phase. SANS data obtained were interpreted with particle interaction model using Baxter sticky spheres model.

    • Small angle neutron scattering study of doxorubicin–surfactant complexes encapsulated in block copolymer micelles

      Jayita Bhattacharjee Gunjan Verma V K Aswal P A Hassan

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      Self-assembling behaviour of block copolymers and their ability to evade the immune system through polyethylene oxide stealth makes it an attractive candidate for drug encapsulation. Micelles formed by polyethylene oxide–polypropylene oxide–polyethylene oxide triblock copolymers (PEO–PPO–PEO), pluronic P123, have been employed for encapsulating the anti-cancer drug doxorubicin hydrochloride. The binding affinity of doxorubicin within the micelle carrier is enhanced through complex formation of drug and anionic surfactant, aerosol OT (AOT). Electrostatic binding of doxorubicin with negatively charged surfactants leads to the formation of hydrophobic drug–surfactant complexes. Surfactant-induced partitioning of the anti-cancer drug into nonpolar solvents such as chloroform is investigated. SANS measurements were performed on pluronic P123 mi-celles in the presence of drug–surfactant complex. No significant changes in the structure of the micelles are observed upon drug encapsulation. This demonstrates that surfactant–drug complexes can be encapsulated in block copolymer micelles without disrupting the structure of aggregates.

    • Tuning intermicellar potential of Triton X-100– anthranilic acid mixed micelles

      Gunjan Verma V K Aswal S K Kulshreshtha C Manohar P A Hassan Eric W Kaler

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      Structural parameters of micelles formed by Triton X-100 in the presence of solubilized anthranilic acid at different pH values was investigated using light scattering and small angle neutron scattering. Analysis of the SANS data indicate that micelles are oblate ellipsoidal in nature with little variation in the dimensions, in the investigated pH range (from 0.5 to 6.0). The interaction potential of the micelles shows a minimum closer to the isoelectric point of anthranilic acid. A similar variation is observed in the cloud point of the micelles with pH. The observed variation in the interaction potential with pH of the micellar solution can be explained in terms of the reversal of charge on anthranilic acid due to shift in the acid–base equilibrium. The variation in interaction potential and cloud point with pH is modelled using Coulombic repulsion of charged molecules at the micelle interface.

    • Structural investigation of viscoelastic micellar water/CTAB/NaNO3 solutions

      K Kuperkar L Abezgauz D Danino G Verma P A Hassan V K Aswal D Varade P Bahadur

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      A highly viscoelastic worm-like micellar solution is formed in hexa-decyltrimethylammonium bromide (CTAB) in the presence of sodium nitrate (NaNO3). A gradual increase in micellar length with increasing NaNO3 was assumed from the rheological measurements where the zero-shear viscosity ($\eta_{0}$) versus NaNO3 concentration curve exhibits a maximum. However, upon increase in temperature, the viscosity decreases. Changes in the structural parameters of the micelles with addition of NaNO3 were inferred from small angle neutron scattering measurements (SANS). The intensity of scattered neutrons in the low 𝑞 region was found to increase with increasing NaNO3 concentration. This suggests an increase in the size of the micelles and/or decrease of intermicellar interaction with increasing salt concentration. Analysis of the SANS data using prolate ellipsoidal structure and Yukawa form of interaction potential between mi-celles indicate that addition of NaNO3 leads to a decrease in the surface charge of the ellipsoidal micelles which induces micellar growth. Cryo-TEM measurements support the presence of thread-like micelles in CTAB and NaNO3.

    • Small angle neutron scattering study on the aggregation behaviour of PEO–PPO–PEO copolymers in the presence of a hydrophobic diol

      B Bharatiya V K Aswal P Bahadur

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      Small angle neutron scattering (SANS) measurements on aqueous solutions of four polyethylene oxide–polypropylene oxide–polyethylene oxide block copolymers (commercially known as Pluronic®)F88, P85, F127 and P123 in the presence of hydrophobic C14Diol (also known as Surfynol® 104) reveal information on micellization, micellar size and micellar transitions. While most hydrophilic F88 (with least PPO/PEO ratio) remained unimers in water at 30◦ C, other copolymers formed micellar solutions. Surfynol® 104 is sparingly soluble in water to only about $\sim 0.1$ wt%, but on addition to pluronic solution, it gets incorporated in the micellar region of block copolymer which leads to increase in aggregation number and transformation of spherical to ellipsoidal micelles. The added diol-induced micellization in F88, though hydrophilic copolymers F88 and F127 did not show any appreciable micellar growth or shape changes as observed for P85 and P123 (which are comparatively more hydrophobic). The SANS results on copolymer pairs with same molecular weight PPO but different % PEO (viz. F88 and P85, F127 and P123) and with same molecular weight PEO but different PPO (F88 and F127) reveal that the copolymer with large PPO/PEO ratio facilitate micellar transition in the presence of diol. An increase in temperature and presence of added electrolyte (sodium chloride) in the solution further enhances these effects. The micellar parameters for these systems were found out using available software and are reported.

    • SMARTer for magnetic structure studies

      E G R Putra A Ikram J Kohlbrecher

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      SMARTer, a 36-meter small angle neutron scattering (SANS) spectrometer was installed at the Neutron Scattering Laboratory (NSL), National Nuclear Energy Agency of Indonesia – BATAN in Serpong, Indonesia and has performed the experiment for studying the magnetic structures of Cu(NiFe), CuCo and FeSiBNbCu metal alloys. The experiments were conducted at room temperature and up to 1 T (10 kOe) of external magnetic field. At zero fields, isotropic scattering identified as nuclear scattering is dominant. When a magnetic field is applied in a horizontal direction perpendicular to the neutron beam, the response of the magnetic scattering permits extraction of the field-induced re-arrangement of the magnetic moment. With increasing field the distortion is more pronounced and the magnetic scattering dominates the intensity and affects the peak position. Radial and angular averaging from experimental data are given to show the details of magnetic structures.

    • Small angle neutron scattering studies on protein denaturation induced by different methods

      S Chodankar V K Aswal J Kohlbrecher R Vavrin A G Wagh

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      Small angle neutron scattering (SANS) has been used to study conformational changes in protein bovine serum albumin (BSA) as induced by varying temperature and in the presence of protein denaturating agents urea and surfactant. BSA has pro-late ellipsoidal shape and is found to be stable up to 60°C above which it denaturates and subsequently leads to aggregation. The protein solution exhibits a fractal structure at temperatures above 64°C, with fractal dimension increasing with temperature. BSA protein is found to unfold in the presence of urea at concentrations greater than 4 M and acquires a random coil Gaussian chain conformation. The conformation of the unfolded protein in the presence of surfactant has been determined directly using contrast variation SANS measurements by contrast matching surfactant molecules. The protein acquires a random coil Gaussian conformation on unfolding with its radius of gyration increasing with increase in surfactant concentration

    • Small angle neutron scattering studies on the interaction of cationic surfactants with bovine serum albumin

      Nuzhat Gull S Chodankar V K Aswal Kabir-Ud-Din

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      The structure of the protein–surfactant complex of bovine serum albumin (BSA) and cationic surfactants has been studied by small angle neutron scattering. At low concentrations, the CTAB monomers are observed to bind to the protein leading to an increase in its size. On the other hand at high concentrations, surfactant molecules aggregate along the unfolded polypeptide chain of the protein resulting in the formation of a fractal structure representing a necklace model of micelle-like clusters randomly distributed along the polypeptide chain. The fractal dimension as well as the size and number of micelles attached to the complex have been determined.

    • Studies on pore morphology of titanium and its oxide by small angle neutron scattering

      P K Tripathy A K Patra P U Sastry

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      Titanium metal bodies have been prepared from the sintered powder compacts of TiO2 by a novel molten salt electrochemical approach, known as FFC Cambridge process. The phase and compositional characterizations of both Ti and TiO2 have been carried out by X-ray diffraction. The pore morphologies of sintered TiO2 pellet and the metallic Ti pellet, obtained after electrochemical reduction have been studied by SANS over a scattering wave vector q range of $0.003–3.5$ nm-1 using a double crystal diffractometer and a pin-hole collimated SANS instrument. In the case of reduced metal pellet, average pore size was found to be larger than that of the oxide pellet as the voids left behind after the oxygen atoms left the oxide matrix, could not coalesce.

    • Small angle neutron scattering study of mixed micelles of oppositely charged surfactants

      J V Joshi V K Aswal P S Goyal

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      Structures of mixed micelles of oppositely charged surfactants dodecyltrimethylammonium bromide (DTAB) and sodium dodecyl sulphate (SDS) have been studied using small angle neutron scattering. The concentration of one of the components was kept fixed (0.3 M) and that of another varied in the range 0 to 0.1 M. The aggregation number and micellar size increase and fractional charge decreases dramatically with the addition of small amount of oppositely charged surfactant. The effect of addition of SDS on DTAB is significantly different from that of the addition of DTAB on SDS. The contrast variation SANS experiments using deuterated surfactant suggests the homogeneous mixing of two components in mixed micellar system.

    • Small angle neutron scattering study of temperature-independent formulation of mixed micellar structures

      V K Aswal A G Wagh

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      SANS measurements have been performed on mixed systems of ionic surfactant sodium dodecyl sulphate (SDS) and nonionic surfactant polyoxyethylene 10 lauryl ether (C12E10). The total concentration of the mixed system was kept fixed (10 wt%) and the ionic to nonionic surfactant ratio varied in the range 0 to 1. The temperature effect on the structures of mixed micelles has been studied for temperatures between 30 and 75° C. Micelles of pure ionic and nonionic surfactants show opposite trends when the temperature is increased. Sizes of pure ionic micelles decrease and those of nonionic micelles increase with increase in temperature. We show a formulation balancing these two effects which is temperature-independent and consists of about 25% of ionic surfactants in the mixed system. Contrast variation SANS measurements by contrast matching one of the surfactant components to the solvent suggest homogeneous single mixed micelles of the two components in the mixed systems.

    • Pressure-induced structural transition of nonionic micelles

      V K Aswal R Vavrin J Kohlbrecher A G Wagh

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      We report dynamic light scattering and small angle neutron scattering studies of the pressure-induced structural transition of nonionic micelles of surfactant polyoxyethylene 10 lauryl ether (C12E10) in the pressure range 0 to 2000 bar. Measurements have been performed on 1 wt% C12E10 in aqueous solution with and without the addition of KF. Micelles undergo sphere to lamellar structural transitions as the pressure is increased. On addition of KF, rod-like micelles exist at ambient pressure, which results in rod-like to lamellar structural transition at a much lower pressure in the presence of KF. Micellar structural transitions have been observed to be reversible.

    • Small angle neutron scattering study of pore microstructure in ceria compacts

      A K Patra P U Sastry Srirupa T Mukherjee Vinila Bedekar A K Tyagi

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      Ceria powders were prepared by gel combustion process using cerium nitrate and hitherto unexplored amino acids such as aspartic acid, arginine and valine as fuels. The powders have been characterized by X-ray and laser diffraction. Cold pressed compacts of these powders have been sintered at 1250°C for 2 h. Internal pore microstructure of the sintered compacts has been investigated by small angle neutron scattering (SANS) over a scattering wave vector 𝑞 range of 0.003–0.17 nm-1. The SANS profiles indicate surface fractal morphology of the pore space with fractal dimensionality lying between 2.70 and 2.76.

    • A small angle neutron scattering study on the mixtures of pluronic L121 and anionic surfactant AOT

      G Ghosh V K Aswal D Varade

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      Small angle neutron scattering (SANS) experiments have been carried out on the micellar solutions containing mixtures of a hydrophobic triblock copolymer (L121, EO5PO68EO5) and a hydrophobic anionic surfactant (AOT, sodium bis(2-ethylhexyl)sulphosuccinate) in water with varying ratio (𝑅) of AOT to L121 for $R = 0.15$, 0.2, 0.3, 0.5 and 0.6. It is known that either L121 or AOT alone forms vesicles in water, but in the mixture with appropriate ratio of the two components a thermodynamically stable, isotropic solution of apparently small micelle-like aggregates is formed. We find that these micelles are prolate ellipsoidal.

    • Structure of Co–Zn ferrite ferrofluid: A small angle neutron scattering analysis

      Prashant Acharya Rucha Desai V K Aswal R V Upadhyay

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      A hydrothermal synthesis route is used to synthesize nanomagnetic particles of Co0.3Zn0.7Fe2O4 ferrite ferrofluids with particle diameter ranging from 5.5–9 nm. XRD analysis shows the formation of a single phase spinel structure. EDX results confirm the stoichiometric composition of the cations. Small angle neutron scattering technique is used to determine the size and size distribution of Co0.3Zn0.7Fe2O4 ferrofluid. The sizes thus obtained are in the range of 5.4 to 8.4 nm. These results are in agreement with magnetic measurements.

    • Small angle neutron scattering and small angle X-ray scattering studies of platinum-loaded carbon foams

      P U Sastry V K Aswal A G Wagh

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      The morphology of carbon nanofoam samples comprising platinum nanoparticles dispersed in the matrix was characterized by small angle neutron scattering (SANS) and small angle X-ray scattering (SAXS) techniques. Results show that the structure of pores of carbon matrix exhibits a mass (pore) fractal nature and the average radius of the platinum particles is about 2.5 nm. The fractal dimension as well as the size distribution parameters of platinum particles varies markedly with the platinum content and annealing temperature. Transmission electron micrographs of the samples corroborate the SANS and SAXS results.

    • Small angle neutron scattering study of two nonionic surfactants in water micellar solutions

      Rajewska Aldona

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      Two classic nonionic surfactants – C14E7 (heptaethylene glycol monotetra-decyl ether) and C10E7 (heptaethylene glycol monodecyl ether) were investigated in heavy water solution for concentration $c = 0.17%$ (dilute regime) at different temperatures in the range $t = 10–35^{\circ}$C by small angle neutron scattering (SANS) method. In the case of C14E7 surfactant – for all temperatures at $c = 0.17%$ there are two axial ellipsoidal micelles with longer axis 15 nm at 10°C and 49.5 nm at 35°C in investigated solutions. For C10E7 surfactant at the same concentration of solution and temperature – two axial ellipsoidal micelles were observed, too. The longer axis is equal to 7.5 nm at 10°C, 9 nm at 20°C and at 35°C this axis is equal to 12 nm. Micelles of C10E7 nonionic surfactant are smaller than those of C14E7 surfactant in the same experimental conditions.

    • Fe and N diffusion in nitrogen-rich FeN measured using neutron reflectometry

      Mukul Gupta A Gupta A Wildes T Gutberlet

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      Grazing incidence neutron reflectometry provides an opportunity to measure the depth profile of a thin film sample with a resolution <1 nm, in a non-destructive way. In this way the diffusion across the interfaces can also be measured. In addition, neutrons have contrast among the isotopes, making it feasible to measure the self-diffusion. In the present work, the isotope multilayers of [FeN/57 FeN]10 and [FeN/Fe15N]10 were prepared using magnetron sputtering and self-diffusion of Fe and N was investigated. It was found that N diffusion is slower compared to Fe and does not follow the atomic size dependence.

    • Structure and magnetism of Ni/Ti multilayers on annealing

      Surendra Singh Saibal Basu P Bhatt

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      Neutron reflectometry study has been carried out in unpolarized (NR) and polarized (PNR) mode to understand the structure and magnetic properties of alloy formation at the interfaces of Ni/Ti multilayers on annealing. The PNR data from annealed sample shows a noticeable change with respect to the as-deposited sample. These changes are: a prominent shift of the multilayer Bragg peak to a higher angle and a decrease in the intensity of the Bragg peak. The PNR data from annealed sample revealed the formation of magnetically dead alloy layers at the interfaces. Changes in roughness parameters of the interfaces on annealing were also observed in the PNR data.

    • Scattering length density profile of Ni film under controlled corrosion: A study in neutron reflectometry

      Surendra Singh A K Poswal S K Ghosh Saibal Basu

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      We report the density depth profile of an as-deposited Ni film and density profile for the same film after controlled electrochemical corrosion by chloride ions, measured by unpolarized neutron reflectometry. The neutron reflectometry measurement of the film after corrosion shows density degradation along the thickness of the film. The density profile as a function of depth, maps the growth of pitting and void networks due to corrosion. The profile after corrosion shows an interesting peaking nature.

    • Magnetic depth profiling of Fe/Au multilayer using neutron reflectometry

      Surendra Singh Saibal Basu M Gupta

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      We present unpolarized and polarized neutron reflectometry data on Fe/Au multilayer sample for characterizing the layer structure and magnetic moment density profile. Fe/Au multilayer shows strong spin-dependent scattering at interfaces, making it a prospective GMR material. Fe/Au multilayer with bilayer thickness of 130 Å was grown on Si substrate by RF magnetron sputtering technique. Unpolarized neutron reflectivity measurement yields nuclear scattering length density profile. The magnetic scattering length density profile has been obtained from polarized neutron reflectivity measurements.

    • Neutron forward diffraction by single crystal prisms

      Sohrab Abbas Apoorva G Wagh Markus Strobl Wolfgang Treimer

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      We have derived analytic expressions for the deflection as well as transmitted fraction of monochromatic neutrons forward diffracted by a single crystal prism. In the vicinity of a Bragg reflection, the neutron deflection deviates sharply from that for an amorphous prism, exhibiting three orders of magnitude greater sensitivity to the incidence angle. We have measured the variation of neutron deflection and transmission across a Bragg reflection, for several single crystal prisms. The results agree well with theory.

    • Pancharatnam geometric phase originating from successive partial projections

      Sohrab Abbas Apoorva G Wagh

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      The spin of a polarized neutron beam subjected to a partial projection in another direction, traces a geodesic arc in the 2-sphere ray space. We delineate the geometric phase resulting from two successive partial projections on a general quantal state and derive the direction and strength of the third partial projection that would close the geodesic triangle. The constraint for the three successive partial projections to be identically equivalent to a net spin rotation regardless of the initial state, is derived.

    • Magnetization in permalloy thin films

      Rachana Gupta Mukul Gupta Thomas Gutberlet

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      Thin films of permalloy (Ni80Fe20) were prepared using an Ar+N2 mixture with magnetron sputtering technique at ambient temperature. The film prepared with only Ar gas shows reflections corresponding to the permalloy phase in X-ray diffraction (XRD) pattern. The addition of nitrogen during sputtering results in broadening of the peaks in XRD pattern, which finally leads to an amorphous phase. The $M-H$ loop for the sample prepared with only Ar gas is matching well with the values obtained for the permalloy. For the samples prepared with increased nitrogen partial pressure the magnetic moment decreased rapidly and the values of coercivity increased. The polarized neutron reflectivity measurements (PNR) were performed in the sample prepared with only Ar gas and with nitrogen partial pressure of 5 and 10%. It was found that the spin-up and spin-down reflectivities show exactly similar reflectivity for the sample prepared with Ar gas alone, while PNR measurements on 5 and 10% sample show splitting in the spin-up and spin-down reflectivity.

    • Inelastic neutron scattering and lattice dynamics of NaNbO3 and Sr0.70Ca0.30TiO3

      S K Mishra R Mittal N Choudhury S L Chaplot D Pandey

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      NaNbO3 and (Sr,Ca)TiO3 exhibit an unusual complex sequence of temperature- and pressure-driven structural phase transitions. We have carried out lattice dynamical studies to understand the phonon modes responsible for these phase transitions. Inelastic neutron scattering measurements using powder samples were carried out at the Dhruva reactor, which provide the phonon density of states. Lattice dynamical models have been developed for SrTiO3 and CaTiO3 which have been fruitfully employed to study the phonon spectra and vibrational properties of the solid solution (Sr,Ca)TiO3.

    • Lattice dynamics of strontium tungstate

      Prabhatasree Goel R Mittal S L Chaplot A K Tyagi

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      We report here measurements of the phonon density of states and the lattice dynamics calculations of strontium tungstate (SrWO4). At ambient conditions this compound crystallizes to a body-centred tetragonal unit cell (space group I41/a) called scheelite structure. We have developed transferable interatomic potentials to study the lattice dynamics of this class of compounds. The model parameters have been fitted with respect to the experimentally available Raman and infra-red frequencies and the equilibrium unit cell parameters. Inelastic neutron scattering measurements have been carried out in the triple-axis spectrometer at Dhruva reactor. The measured phonon density of states is in good agreement with the theoretical calculations, thus validating the inter-atomic potential developed.

    • Inelastic neutron scattering and lattice dynamics of ZrO2, Y2O3 and ThSiO4

      Preyoshi P Bose R Mittal N Choudhury S L Chaplot

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      Zirconia (ZrO2), yttria (Y2O3) and thorite (ThSiO4) are ceramic materials used for a wide range of industrial applications. The dynamical properties of these materials are of interest as they exhibit numerous interesting phase transitions at high temperature and pressure. Using a combination of inelastic neutron scattering and theoretical lattice dynamics we have studied the phonon spectra and thermodynamic properties of these compounds. The experimental data validate the theoretical model, while the model enables microscopic interpretations of the observed data. The calculated thermodynamic properties are in good agreement with the experimental data.

    • Lattice dynamics of ferromagnetic superconductor UGe2

      Satyam Shinde Prafulla K Jha

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      This paper reports the lattice dynamical study of the UGe2 using a lattice dynamical model theory based on pairwise interactions under the framework of the shell model. The calculated phonon dispersion curves and phonon density of states are in good agreement with the measured data.

    • Diffusion of propylene adsorbed in Na-Y and Na-ZSM5 zeolites: Neutron scattering and FTIR studies

      S Gautam A K Tripathi V S Kamble S Mitra R Mukhopadhyay

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      Here we report the quasielastic neutron scattering and FTIR studies on the dynamics of propylene adsorbed in Na-Y and Na-ZSM5 zeolites. QENS data show that although the mechanism of translational motion of propylene is jump diffusion in both the cases of Na-Y and Na-ZSM5 zeolites, the diffusivity is affected by the host size and is hindered in the case of Na-ZSM5. FTIR studies showed that guest–host interaction in Na-ZSM5 is stronger than that in Na-Y zeolite corroborating the QENS results.

    • Phase transitions in liquid crystal 6O.4 (p-𝑛-hexyloxybenzylidine-pˊ-𝑛-butylaniline)

      Siddharth Gautam R R Choudhury L Panicker S Mitra R Mukhopadhyay

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      DSC measurements on p-𝑛-hexyloxybenzylidine-pˊ-𝑛-butylaniline (6O.4) showed that the crystalline to liquid crystalline ($K–S_{\text{H}}$) transition at 33.7°C observed in the heating cycle does not revert even when the sample is cooled down to −100°C. Hence it is inferred that a physically stable supercooled liquid crystalline phase is formed on cooling 6O.4. To investigate the $K–S_{\text{H}}$ transition further the techniques of polarized microscopy and X-ray diffraction were used which concurred with the DSC results. Quasi-elastic neutron scattering measurements carried out to study the re-orientational motions in the ordered phases of 6O.4 (𝐾 and $S_{\text{H}}$) show that while in the crystalline phase (at RT) the re-orientational motion is found to involve only the core of the molecule, in the $S_{\text{H}}$ phase (at 45°C) the dynamics involves the whole molecule and this motion is found to persist even when the sample cools back to room temperature corroborating the results of the DSC, microscopy and X-ray diffraction.

    • Rotational dynamics of propylene inside Na-Y zeolite cages

      V K Sharma Mala N Rao Siddharth Gautam A K Tripathi V S Kamble S L Chaplot R Mukhopadhyay

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      We report here the quasielastic neutron scattering (QENS) studies on the dynamics of propylene inside Na-Y zeolite using triple axis spectrometer (TAS) at Dhruva reactor, Trombay. Molecular dynamics (MD) simulations performed on the system had shown that the rotational motion involves energy larger than that involved in the translational motion. Therefore, rotational motion was not observed in our earlier QENS studies on propylene adsorbed Na-Y zeolite using a higher resolution spectrometer at Dhruva. Analysis of the TAS spectra revealed that the quasielastic broadening observed in propylene-loaded zeolite spectra is due to the rotational motion of the propylene molecules. This is consistent with our simulation result. Further, the rotational motion is found to be isotropic. The rotational diffusion coefficient has been obtained.

    • Bragg prism monochromator and analyser for super ultra-small angle neutron scattering studies

      Apoorva G Wagh Sohrab Abbas Markus Strobl Wolfgang Treimer

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      We have designed, fabricated and operated a novel Bragg prism monochromator–analyser combination. With a judicious choice of the Bragg reflection, its asymmetry and the apex angle of the silicon single crystal prism, the monochromator has produced a neutron beam with sub-arcsec collimation. A Bragg prism analyser with the opposite asymmetry has been tailored to accept a still sharper angular profile. With this optimized monochromator–analyser pair, we have attained the narrowest and sharpest neutron angular profile to date. At this facility, we have recorded the first SUSANS spectra spanning wave vector transfers $Q \sim 10^{−6}$ Å-1 to characterize samples containing agglomerates up to tens of micrometres in size.

    • Effect of adding Ar gas on the pulse height distribution of BF3-filled neutron detectors

      M Padalakshmi A M Shaikh

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      Boron trifluoride (BF3) proportional counters are used as detectors for thermal neutrons. They are characterized by high neutron sensitivity and good gamma discriminating properties. Most practical BF3 counters are filled with pure boron trifluoride gas enriched up to 96% 10B. But BF3 is not an ideal proportional counter gas. Worsening of plateau characteristics is observed with increasing radius due to impurities in gas. To overcome this problem, counters are filled with BF3 with an admixture of a more suitable gas such as argon. The dilution of BF3 with argon causes a decrease in detection efficiency, but the pulse height spectrum shows sharper peaks and more stable plateau characteristics than counters filled with pure BF3. The present investigations are under-taken to study the pulse height distribution and other important factors in BF3+Ar filled signal counters for neutron beam applications. Tests are performed with detectors with cylindrical geometry filled with BF3 gas enriched in 10B to 90%, and high purity Ar in different proportions. By analysing pulse height spectra, a value of $6.1 \pm 0.2$ has been obtained for the branching ratio of the 10B($n,\alpha$) reaction.

    • Performance studies on high pressure 1-D position sensitive neutron detectors

      S S Desai A M Shaikh

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      The powder diffractometer and Hi-Q diffractometer at Dhruva reactor make use of five identical 1-D position sensitive detectors (PSDs) to scan scattering angles in the range 3° to 140°. In order to improve the overall throughput of these spectrometers, it is planned to install a bank of 15 high-efficiency and high-resolution PSDs arranged in three layers with five PSDs in each layer. With each high pressure PSD (3He 10 bar + Kr 2 bar) showing the efficiency gain of 1.8 at 1.2 Å, detector bank is expected to show overall gain of 5.5 times the present detection efficiency and reduction in data collection time by equivalent factor. The 1-D PSDs are developed in batches of five, and are characterized so that all PSDs operate at uniform parameters such as position resolution, uniformity of efficiency and linearity of response. Position spectrum indicates the differential position resolution to be $\sim 1$ mm and integral position resolution to be 3–4 mm. Broadening of position spectrum at the extreme end of sensitive length of PSD is analysed using fine shift of the beam. Dependence of position resolution and dynamic range of output pulse on the input impedance of pre-amplifier is also presented.

    • Neutron detectors for scattering experiments at HANARO

      Myungkook Moon Changhee Lee Jongkyu Cheon Younghyun Choi Harkrho Kim Shraddha S Desai

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      Position sensitive detectors (PSD) measure the distribution of scattered neutrons and are essential tools for neutron scattering experiments. Various types of neutron detectors used at neutron diffractometers are conventional tube detectors, 1-D and 2-D PSDs. Korea Atomic Energy Research Institute (KAERI) has been developing various kinds of PSDs to improve the instrument performance and to develop new scattering instruments. Our development work is initiated with 1-D PSD for residual stress analysis spectrometer and finally the technology is extended to development of 2-D PSD with planar and curved geometry. All PSDs are based on multiwire grid assembly with delay line readout method for position encoding, as the response is faster than charge division method and enables higher count rate capability. Design details and operational characteristics of some of the PSDs developed, for application at neutron scattering instruments are presented.

    • A high resolution powder diffractometer using focusing optics

      V Siruguri P D Babu M Gupta A V Pimpale P S Goyal

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      In this paper, we describe the design, construction and performance of a new high resolution neutron powder diffractometer that has been installed at the Dhruva reactor, Trombay, India. The instrument employs novel design concepts like the use of bent, perfect crystal monochromator and open beam geometry, enabling the use of smaller samples. The resolution curve of the instrument was found to have little variation over a wide angular region and a $\Delta d/d \sim 0.3%$ has been achieved. The instrument provides sample environment of very low temperatures and high magnetic fields using a 7 Tesla cryogen-free superconducting magnet with a VTI having a temperature range of 1.5–320 K. The special sample environment and high resolution make this neutron powder diffractometer a very powerful facility for studying magnetic properties of materials.

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