Volume 122, Issue 1
February 2013, pages 1-269
pp 1-13 February 2013
India is a country of particular interest with regard to its future water resources, as it is expected to undergo continued rapid population growth while also being especially sensitive to climate change. The Land-surface Processes and eXchanges Dynamic Global Vegetation Model (LPX-DGVM) is used here to simulate present and future runoff in India using ClimGen pattern-scaled scenarios of 1°, 2° and 4°C temperature increase (scaled to 2050) forced by six general circulation models (GCMs). As is the case with many DGVMs, groundwater storage is not simulated by LPX, so in order to form a more comprehensive understanding of water resources, Gravity Recovery and Climate Experiment (GRACE) satellite estimates for north-west India are incorporated into this study and compared to LPX runoff simulations. Runoff is simulated to have increased slightly (1.5 mm/year) in this region during 2002–2006, while groundwater extractions appear to have been made at rates of 40 ± 10 mm/year.
North-west India is simulated to experience considerable increases in runoff by 2070–2099, with a mean change of 189 mm/year for 2°C climate change (although the range of model results, 247 mm/year, demonstrates high uncertainty among GCMs). Precipitation is shown to have an important bearing on runoff generation, while the degree of warming is shown to affect the magnitude of future runoff. This may subsequently influence the longevity of the local groundwater resource. However, at recent rates of depletion and in view of expected population growth, the long-term sustainability of groundwater reserves in north-west India is in doubt.
pp 15-28 February 2013
The chemical composition of groundwater within the multilayer Jeffara aquifer and the detailed analysis of saturation indices enables identification of the origin of mineralization and hydrogeochemical processes occurring in groundwater. It has been demonstrated that groundwater is mainly characterized by a Ca–Mg–SO4–Cl water type. Geochemical pattern is controlled by the dissolution of evaporites, largely abundant in the study area and incongruent dissolution of dolomite. Gypsum, anhydrite, mirabilite and thenardite have been examined as potential sources of sulphate dissolved in groundwater. Since Jeffara groundwater is recharged by the Continental Intercalaire (CI) geothermal water, water temperature decreases from the CI to the Jeffara aquifer. Solubility of the majority of minerals is modified by this change in temperature and thus a mixing process of thermal and non-thermal waters was examined.
pp 29-41 February 2013
The region under investigation for groundwater exploration is a part of the eastern fringe of Deccan traps in Kalmeshwar Taluk of Nagpur district. In this region, groundwater is the main source of water supply for drinking and irrigation purposes. Presently, the known source of groundwater is the upper weathered mantle in the depth range of 8–15 m. This source of groundwater has been overexploited because of increasing demand of water supply and is unable to meet the present requirement. The present work deals with the delineation of new sources of groundwater at deeper levels concealed within and below the traps by using vertical electrical sounding surveys in order to meet the increasing demand of water supply.
pp 43-54 February 2013
Najafgarh drain is the biggest drain in Delhi and contributes about 60% of the total wastewater that gets discharged from Delhi into river Yamuna. The drain traverses a length of 51 km before joining river Yamuna, and is unlined for about 31 km along its initial stretch. In recent times, efforts have been made for limited withdrawal of groundwater from shallow aquifers in close vicinity of Najafgarh drain coupled with artificial recharge of groundwater. In this perspective, assessment of groundwater quality in shallow aquifers in vicinity of the Najafgarh drain of Delhi and hydrogeological characterization of adjacent areas were done. The groundwater quality was examined in perspective of Indian as well as World Health Organization’s drinking water standards. The spatial variation in groundwater quality was studied. The linkages between trace element occurrence and hydrochemical facies variation were also established. The shallow groundwater along Najafgarh drain is contaminated in stretches and the area is not suitable for large-scale groundwater development for drinking water purposes.
pp 55-63 February 2013
Light hydrocarbons in soil have been used as direct indicators in geochemical hydrocarbon exploration, which remains an unconventional path in the petroleum industry. The occurrence of adsorbed soil gases, methane and heavier homologues were recorded in the near-surface soil samples collected from Kutch–Saurashtra, India. Soil gas alkanes were interpreted to be derived from deep-seated hydrocarbon sources and have migrated to the surface through structural discontinuities. The source of hydrocarbons is assessed to be thermogenic and could have been primarily derived from humic organic matter with partial contribution from sapropelic matter. Gas chromatographic analyses of hydrocarbons desorbed from soil samples through acid extraction technique showed the presence of methane through 𝑛-butane and the observed concentrations (in ppb) vary from: methane (C1) from 4–291, ethane (C2) from 0–84, propane (C3) from 0–37, i-butane (iC4) from 0–5 and 𝑛-butane (nC4) from 0–4. Carbon isotopes measured for methane and ethane by GC-C-IRMS, range between −42.9‰ to −13.3‰ (Pee Dee Belemnite – PDB) and −21.2‰ to −12.4‰ (PDB), respectively. The increased occurrence of hydrocarbons in the areas near Anjar of Kutch and the area south to Rajkot of Saurashtra signifies the area potential for oil and gas.
pp 65-78 February 2013
Geochemical studies and modelling show that both volcanic and granitic magmas from the western part of the Johor National Park, Endau Rompin are different and probably have different sources. The geochemical plot suggests that both dacite/rhyolite and andesite probably have a common origin as in many of the geochemical plots, these two groups form a similar trend. Volcanic rocks have a transitional geochemical character between tholeiite and calc alkaline on a Y versus Zr plot. $(La/Yb)_N$ versus La and TiO2 versus Zr modelling show that the crystallization of both granitic and volcanic magmas are controlled by a different set of minerals. The rare earth elements (REE) patterns of some of the granite and volcanic samples have pronounced negative Eu anomaly indicating plagioclase fractionation. The difference between both profiles is that the granite samples show a concave shape profile which is consistent with liquids produced by partial melting of quartz feldspathic rocks containing amphibole among the residual phase. Both magmas were generated at a different time during the subduction of Sibumasu beneath the Indochina blocks.
pp 79-91 February 2013
Ultramafic rocks comprising dunite, harburgite, lehzolite, olivine webserite and websterite occur as intrusives in the form of small hillocks at around Pindar into the granite–gneisses of Bundelkhand Gneissic Complex (BnGC). The peridotites are dominated by olivine cumulates where chromite and precious metal-bearing sulphides crystallized along with pyroxenes, subsequent to crystallization of olivine into the interstitial spaces of cumulates during cooling. Ultramafic rocks of Pindar are characterized by high MgO (up to 46.0 wt%) and FeO (up to 5.8 wt%); low SiO2 (40.8 to 48.0 wt%), TiO2 (0.2 to 0.5 wt%), Al2O3 (∼3.2 wt% av.), CaO(∼ 2.7 wt% av.) and Cu (11 to 73 𝜇 g/g). Cr and Ni values range from 2297 to 3150 𝜇 g/g and 2434 to 2767 𝜇 g/g, respectively. Distribution of Ir (up to 20 ng/g), Ru (27 to 90 ng/g), Rh (3 to 14 ng/g), Pt (18 to 72 ng/g), Pd (10 to 27 ng/g) and Au (22 to 57 ng/g) indicate platinum group element (PGE) and associated gold mineralization in these ultramafic rocks. A mineral phase representing sperrylite (PtAs2) was also identified within the sulphides in Scanning electron microscopy with energy dispersive spectrometer (SEM–EDS) studies. The primitive mantle-normalized siderophile elements pattern shows platinum group element PGE (PPGE) enrichment (Rh, Pt, Pd). Discrimination diagrams of Pd/Ir vs. Ni/Cu, Pd/Pt vs. Ni/Cu, Cu/Pd vs. Pd, and Cu vs. Pd for the peridotites of Pindar attribute to affinity towards komatiite magma, derived from high degree of partial melting of prolonged depleted mantle, and the sulphur saturation condition incurred during the crystallization of chromite which was favourable for PGE mineralization.
pp 93-106 February 2013
This work illustrates the efficiency of field spectroscopy for rapid identification of minerals in ore body, alteration zone and host rocks. The adopted procedure involves collection of field spectra, their processing for noise, spectral matching and spectral un-mixing with selected library end-members. Average weighted spectral similarity and effective peak matching techniques were used to draw end-members from library. Constrained linear mixture modelling technique was used to convolve end-member spectra. Linear mixture model was optimized based on root mean square error between field- and modelled-spectra. Estimated minerals and their abundances were subsequently compared with conventional procedures such as petrography, X-ray diffraction and X-ray fluorescence for accuracy assessment. The mineralized zone is found to contain azurite, galena, chalcopyrite, bornite, molybdenite, marcacite, gahnite, hematite, goethite, anglesite and malachite. The alteration zone contains chlorite, kaolinite, actinolite and mica. These mineral assemblages correlate well with the petrographic measurements ($R^2 = 0.89$). Subsequently, the bulk chemistry of field samples was compared with spectroscopically derived cumulative weighted mineral chemistry and found to correlate well ($R^2 = 0.91–0.98$) at excellent statistical significance levels (90–99%). From this study, it is evident that field spectroscopy can be effectively used for rapid mineral identification and abundance estimation.
pp 107-122 February 2013
Seismic hazard assessment of any region depends on the attenuation relation which relates the seismological data with parameters of engineering interest. In the absence of sufficient strong motion data for northwest Himalayan region, isoseismal maps of previous earthquakes were the only source of information for computing the attenuation characteristics of that region. The northwest Himalayan region had experienced major and moderate earthquakes in the past and isoseismal maps had been developed by various authors for each of these earthquakes representing intensity pattern and decay of intensity in different directions. With this information, attenuation relations of intensity with distance can be obtained. The present study includes 10 moderate and major earthquakes ($M_s$ ≥ 4.9) that had occurred during the last 100 years. These are primarily Kangra (1905), Chamba-1 (1945), Chamba-2 (1995), Kinnaur (1975), Dharamsala (1986), Uttar Kashi (1991), Garhwal-1 (1996), Garhwal-2 (1996), Sundarnagar (1997) and Chamoli (1999) earthquakes. Miezoseismal zones in majority of the isoseismal maps show two major directions, i.e., either the longest axis of these isoseismal maps which are aligned in NW–SE direction following the major longitudinal features or north-northwest to south-southeast direction, following the tectonic features which are transverse to the Himalayan trend. Isoseismal maps of Kangra (1905), Chamba (1945) and Uttar Kashi (1991) earthquakes are more symmetrical and elongated in south-east direction, but compressed in north-east and north-west directions, thus indicating fast attenuation characteristics in north-east and north-west directions reflecting lithological variation. On the other hand, Sundernagar (1997) and Kinnuar (1975) earthquakes show circular pattern of intensity distribution. Combining decay patterns from different magnitude earthquakes in different directions, two attenuation relationships have been developed using regression relationship (least square method).
pp 123-136 February 2013
Seventy-two microtremor measurements were conducted in the northern coast of İzmir Bay. The dataset has been processed using the horizontal-to-vertical spectral ratio. The fundamental period contour map obtained showed that the fundamental period at rock sites of the northern coast of İzmir Bay was between 0.15 and 0.35 s. However, the fundamental period increased towards the western direction where thick soft sediments exist, the fundamental period varied between 0.5 and 2.0 s. A soil classification map of the area was prepared based on the data estimated from SPT-𝑁 values of 25 boreholes. It is seen that major portion of the study area, including the shore line of the northern coast had SPT-𝑁 values lower than 15. The fundamental periods obtained by H/V spectral ratio method and the periods derived from shear wave velocity data available in 11 of 25 boreholes were well-correlated. Fundamental period map obtained from H/V spectral ratio method illustrated the characteristics of weak soil conditions and the presence of bedrock level under thick alluvial soils. Finally, microtremor investigations have proved to be an effective tool for assessment of local soil conditions in case of thick soft sediments in the northern coast of İzmir Bay.
pp 137-147 February 2013
The Northeast Japan arc, a mature volcanic arc with a back-arc marginal basin (Japan Sea), is located on a convergent plate boundary along the subducting Pacific plate and the overriding North American plate. From a compilation and analysis of stratigraphy, radiometric age and data on erupted magma volumes, 176 eruptive episodes identified from 69 volcanoes so far, indicate that notable changes in eruption style, magma discharge rates and distribution of eruptive centres occurred around 1.0 Ma. Before ca.1.0 Ma, large-volume felsic eruptions were dominant, forming large calderas in the frontal arc, a region of low crustal strain rate. After ca. 1.0 Ma to the present, the calc-alkaline andesite magma eruptions in the frontal and rear arcs, synchronous with crustal shortening characterized by reverse faulting, resulted in stratovolcano development along narrow uplifted zones. Although, it is widely assumed that magma cannot rise easily in a compressional setting, some of the magma stored within basal sills could be extruded where N–S-trending uplifted mountains bounded by reverse faults formed since about ca.1.0 Ma.
pp 149-161 February 2013
Five species of Steginoporella from the Palaeogene rocks of the Western Kachchh, Gujarat are described in this paper. Out of five steginoporellids, S. mathuri n.sp., S. murachbanensis n.sp. and S. chiplonkari n.sp. are new to science; S. bhujensis is already reported from this region; and Steginoporella sp. indet is reported for the first time in these rocks. All these species show Indo-Pacific affinities. The occurrence of Steginoporella from Middle Eocene to Early Miocene indicates that two stages of radiation had taken place in Kachchh. Phylogenetic analysis using PAST programme indicates that S. mathuri is very distinct from other species of Steginoporella; while S. murachbanensis and S. bhujensis form the same clade.
pp 163-171 February 2013
Late Paleocene to early Eocene (∼56 to 51 Ma) interval is characterized by five distinct transient warming (hyperthermal) events (Paleocene–Eocene thermal maximum (PETM), H1/ETM2/ELMO, H2, I1 and I2) in a super greenhouse globe associated with negative carbon isotope excursions (CIEs). Although well-documented marine records exist at different latitudes, terrestrial PETM sections are rare. In particular, almost no terrestrial records of either the PETM or early Eocene hyperthermals (EEHs) are yet available from the tropics. Further, evolution of modern order of mammals near the PETM has been recorded in many northern continents; however, the response of mammals in the tropics to these warming events is unknown. A tropical terrestrial record of these hyperthermal/CIE events, encompassing the earliest modern order mammal bearing horizon from India, can therefore be vital in understanding climatic and biotic evolution during the earliest Cenozoic time. Here, for the first time, we report high resolution carbon isotope (𝛿13C) stratigraphy, nannofossil, and Sr isotope ratio of marine fossil carbonate from the Cambay Shale Formation of Western India. The record shows complete preservation of all the above CIE events, including the PETM, hitherto unknown from the equatorial terrestrial records. 𝛿13C chemostratigraphy further suggests that at least the present early Eocene mammal-bearing horizon, recently discovered at Vastan, does not support the ‘out of India’ hypothesis of earliest appearance of modern mammals and subsequent dispersal to the Holarctic continents.
pp 173-185 February 2013
A gravity core SK-221 recovered from the southeastern Arabian Sea near Laccadive–Chagos Ridge was examined to identify the sources of detrital clay minerals and to decipher paleoenvironmental changes for the last 30 kyr. The clay mineral assemblages predominantly consist of illite, kaolinite and chlorite with small amounts of smectite. Quartz, feldspar and occasionally gibbsite are the clay-sized non-clay minerals present in the examined section. The detrital clay minerals primarily originated from the hinterland and were supplied to the present site by the numerous small rivers draining western India during preglacial and Holocene periods, and partly by the strong reworking of Indian continental shelf during glacial period. The low values of humidity proxies (kaolinite content, kaolinite to illite and smectite to illite ratios) and better illite crystallinity indicate relatively weak summer monsoon condition that resulted in reduced chemical weathering during glacial period, which was interrupted by a discrete event of winter monsoon intensification at ∼20–17 ka. The increased kaolinite content, higher values of humidity indices and poorer illite crystallinity reflect high humidity that resulted in strong hydrolysis activity during the preglacial and Holocene periods. The increased CaCO3 during above periods also indicates less terrigenous dilution and intensified southwest monsoon-led upwelling which result in higher surface biogenic productivity. The characteristic clay mineral associations broadly suggest dry to semi-drier conditions during Heinrich Events H1, H2, and H3 and also during Younger Dryas. The low values of biogenic carbonate and organic carbon also indicate low productivity associated with weak summer monsoons during Heinrich Events. Abrupt increased humidity was recorded at 15–12.7 ka (Bølling/Allerød Event) sandwiched between two lows of Heinrich Events. Cycles of millennial timescale variations 2300, 1800, 1300 and 1000 yr have been observed from the clay mineralogical data. All the cycles observed in the monsoonal climate appear to be part of global oscillations.
pp 187-199 February 2013
The OSCAR (ocean surface current analysis real-time),which is a product derived from various satellite observations,has been evaluated in the tropical Indian Ocean (TIO)in two di ﬀerent ways.First,the OSCAR-derived monthly climatology has been compared with available drifter-derived climatology in the TIO.From the comparison of the two climatologies,one can infer that OSCAR product is able to capture the variabilities of the well-known surface current systems in the TIO reasonably well.Fourier analysis of the major current systems,as reproduced by OSCAR,shows that the dominant annual and semiannual periodicities,known to exist in these systems,have been faithfully picked up by OSCAR. Next,the evaluation has been carried out by comparing the OSCAR currents with currents measured by moored buoys.The zonal component of OSCAR-current is in good agreement with corresponding component of buoy-observed current with a correlation exceeding 0.7,while the match between the meridional components is poorer.The locations of the peaks of the mean and eddy kinetic energies are matching in both the climatologies,although the peak in the drifter climatology is stronger than the same in the OSCAR product.Finally,an important feature of Indian Ocean circulation,namely the reverse Wyrtki jet,occurring during anomalous dipole years,has been well-reproduced by OSCAR currents.
pp 201-213 February 2013
To investigate the temperature changes at 100 hPa over Indian region from Arabian Sea (AS) to Bay of Bengal (BOB), analysis is performed using Atmospheric Infra Red Sounder (AIRS) temperature and outgoing long-wave radiation (OLR) data of 9 years (2003–2011). Fine-scale temperature variations have been studied and shown for summer (March–April–May, MAM), summer monsoon (June–July–August–September, JJAS) and winter (November–December–January–February, NDJF) months. Similarities and differences in the latitudinal and longitudinal variation of temperature and the possible causes have been examined. During MAM and NDJF, the temperature increases latitudinally by ∼2–3 K and ∼4–5 K from 3.5° to 20.5°N, respectively. However, the temperature decreases by ∼2.0–2.5 K during JJAS. A similar contrasting behaviour is observed in latitudinal temperature gradient. For MAM and NDJF, the gradient decreases from ∼0.18 to ∼0.14 K/deg and ∼0.25 to ∼0.18 K/deg, respectively, as we move longitudinally from 60° to 90°E; however, for JJAS, it increases from ∼0.10 to ∼0.14 K/deg over the same longitudes. It is found that latitudinal temperature gradient for NDJF is larger by about a factor of 1.5. Analysis suggests latitudinal change in temperature occurs due to low OLR (proxy of convection) and its northward progression during summer monsoon. Correlation coefficient (𝑅_xy) between OLR and temperature is computed latitudinally (3.5° to 20.5°N) at different longitudes and during JJAS (monsoon months), 𝑅xy is negative (∼−0.73) over 60° and 70°E longitudes, but it turns positive (∼0.92) over 80° and 90°E longitudes (which is convectively active region), suggesting a close association between low temperature and low OLR. Land–sea contrast is also observed in temperature at 100 hPa with a slight increase (∼0.5 K) from sea to land.
pp 215-227 February 2013
Insufficient long-term in situ observations and complex topographic conditions pose major problems in quantifying the magnitude of climatic trends in mountainous regions such as Nepal. Presented here is three decades (1980–2009) of data on annual maximum, minimum and average temperature trends from 13 mountain stations on the southern slope of the central Himalayas. The stations are located at elevations between 1304 and 2566 m above sea level and with varied topography. Spatial analyses of the average temperature trend show warming in most of the stations. The magnitude of warming is higher for maximum temperatures, while minimum temperatures exhibit larger variability such as positive, negative or no change. These results are consistent with patterns reported in some parts of the Indian subcontinent and Upper Indus Basin, but different from conditions on the Tibetan Plateau (China), where the warming of minimum temperatures is more prominent than that of the maximum temperatures. From the temporal variations, a dramatic increase in temperature is observed in the latest decade, particularly in the average and maximum temperatures. The results from the cumulative sum chart analyses suggest that the thermal regime shifted in 1997. The dramatic enhancement of average temperature in the last decade is strongly consistent with the result of contemporary studies of the surrounding regions, where warming is attributed to an increase in anthropogenic greenhouse gases. However, as in the western Himalayas and the Upper Indus Basin, the mountain stations on the southern slope of the central Himalayas show variability in temperature trends, particularly for the minimum temperature. This inhomogeneous trend is likely ascribed to the differences in topography and microclimatic regime of the observed stations.
pp 229-237 February 2013
In the present study, the observation of indoor air ion concentration at a rural site has been carried out for the first time. These indoor observations are compared with outdoor air ion concentration. Net charge can be introduced into the atmosphere by processes such as combustion, rainfall and ultraviolet radiation. As compared to indoors, average air ions of both the polarities at outdoors are higher. Moreover, the air ion concentrations, experience large fluctuations during daytime, as compared to nighttime values. Positive and negative air ion concentrations are lower and uniform throughout the night both for indoor and outdoor conditions. Pollution index is more or less unity for outdoors in all-the-time period, which is good for human health. Due to limited sources of air ions indoors, it is observed that pollution index decreases from 00:00–02:00 hours and minimum is reached during 12:00–14:00 hours for indoors. During 00:00–02:00 hours, the indoor pollution index is 1.55, which is very harmful to human health.
pp 239-252 February 2013
A critical analysis has been made on the contribution of CFC-11, CFC-12, CFC-113, CH2Cl, CH3Br, CCl4, CH3CCl3, HCFCs, halons, WMO (World Meteorological Organization) minor constituents, CH4, N2O and water vapour to the variation of total column ozone (TCO) concentration at the station in Srinagar (34°N, 74.8°E), India from 1992 to 2003. With the implementation of Montreal Protocol, though the concentrations of CFC-11, CFC-113, CH3Cl, CH3Br, CCl4 and CH3CCl3 had decreased, the concentrations of CFC-12, HCFCs, halons, WMO minor constituents, CH4, N2O and water vapour had increased, as a result of which TCO had risen from 1992 to 2003 at the above station. The nature of yearly variations of concentrations of the above ozone depleting substances and greenhouse gases as well as ozone has been presented. Possible explanations for build-up of TCO have also been offered.
pp 253-269 February 2013
This paper investigates the role of El Niño-Southern Oscillation (ENSO)-based climate variability in modulating multivariate drought risks in the drought-prone region of Western Rajasthan in India. Droughts are multivariate phenomenon, often characterized by severity, duration and peak. By using multivariate ENSO index, annual drought events are partitioned into three climatic states – El Niño, La Niña and neutral phases. For multivariate probabilistic representation of drought characteristics, trivariate copulas are employed, which have the ability to preserve the dependence structure of drought variables under uncertain environment. The first copula model is developed without accounting the climate state information to obtain joint and conditional return periods of drought characteristics. Then, copula-based models are developed for each climate state to estimate the joint and conditional probabilities of drought characteristics under each ENSO state. Results of the study suggest that the inclusion of ENSO-based climate variability is helpful in knowing the associated drought risks, and useful for management of water resources in the region.
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