• Oxidation studies - IV. Kinetics of oxidation of HCHO and some alcohols by ceric salts in HNO3 medium

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/067/02/0078-0089

    • Keywords

       

      Benzyl Alcohol; Cyclohexanol; HCHO; Allyl Alcohol; Constant Ionic Strength

    • Abstract

       

      The results on the kinetics of oxidation of HCHO and some alcohols,viz.,n-propanol, allyl alcohol, cyclohexanol and benzyl alcohol by ceric nitrate in nitric acid medium in the temperature range of 10–35° C. are presented. The active form of Ce4+ during the oxidation of the above organic substrates was assumed to be the neutral Ce(NO3)4. The mechanism of oxidation and thermodynamic parameters for the above compounds are also given.

    • Author Affiliations

       

      M Santappa1 B Sethuram2

      1. Department of Physical Chemistry, Madras University, Madras-25
      2. Department of Chemistry, Osmania University, Hyderabad
    • Dates

       
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