• New synthesis of tamaraxetin, alpinone and izalpinin

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/047/03/0191-0195

    • Keywords

       

      Hesperidin; Hesperetin; Potassium Acetate; Silver Acetate; Alcoholic Ferric Chloride

    • Abstract

       

      A new and convenient method for the synthesis of tamaraxetin uses hesperetin. By the action of iodine and silver acetate, it is converted into 3-acetoxy-hesperetin and eventually into 3-hydroxy-hesperetin which undergoes dehydrogenation by means of iodine and potassium acetate to yield tamaraxetin.

      5-Hydroxy-7-methoxy-flavanone (pinostrobin) is converted into alpinone by Fenton’s oxidation and subsequent dehydrogenation yields izalpinin.

    • Author Affiliations

       

      R N Goel1 T R Seshadri1

      1. Department of Chemistry, Delhi University, Delhi
    • Dates

       
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