• Synthetic experiments in the benzopyrone series - Part XXVI. A synthesis of 8-methyl isogenistein

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      https://www.ias.ac.in/article/fulltext/seca/037/04/0526-0530

    • Keywords

       

      Genistein; Isoflavone; Phenyl Acetic Acid; Ethyl Formate; Hydriodic Acid

    • Abstract

       

      One of the crystalline compounds occurring in soya beans has been considered by Okano and Beppu to be 8-methyl isogenistein and this structure was based on the alkali degradation of the compound and its trimethyl ether. A compound of this structure is now synthesised starting from 2∶4∶6-trihydroxy-2′-methoxy phenyl benzyl ketone, along the lines of synthesis of 8-methyl genistein described in Part XXII. Here also the products are found to be different from those reported by Okano and Beppu and the natural compound should therefore have a more complex structure.

    • Author Affiliations

       

      T R Seshadri1 S Varadarajan1

      1. Department of Chemistry, University of Delhi, Delhi
    • Dates

       
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