• Kinetic studies in ester hydrolysis - Part VII. Solvent influences

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/036/03/0201-0207

    • Keywords

       

      Dielectric Constant; Ethyl Acetate; Acid Hydrolysis; Solvent Mixture; Alkaline Hydrolysis

    • Abstract

       

      The data obtained in earlier work have been recalculated to give the rate constants under iso-dielectric conditions. These results clearly show that specific solvent effects are present in both acid and alkaline hydrolysis. There is a possible change in the polarisation of the ester molecule with composition in which structural changes in the liquid state presumably play a part.

    • Author Affiliations

       

      S V Anantakrishnan1

      1. Department of Chemistry, Madras Christian College, Tambaram
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