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    • Synthetic experiments in the benzopyrone series - Part XIV. Synthesis of santal

      N Narasimhachari T R Seshadri

      Volume 32 Issue 5 November 1950 pp 342-347

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/032/05/0342-0347

    • Keywords

       

      Ferric Chloride; Acetic Anhydride; Globular Cluster; Aqueous Sodium Hydroxide; Anhydrous Potassium Carbonate

    • Abstract

       

      Santal has been synthesised by methylating 5∶7∶3′∶4′-tetrahydroxy isoflavone with one mole of dimethyl sulphate. When three moles of dimethyl sulphate are employed santal dimethyl ether is obtained. An interesting observation has been made that demethylation of santal trimethyl ether under restricted conditions with hydriodic acid leads to the formation of a mixture of santal and nor-santal. They have been separated using aqueous sodium carbonate.

    • Author Affiliations

       

      N Narasimhachari1 T R Seshadri1

      1. Department of Chemistry, Delhi University, India

    • Dates

       
      Published
      November 1950
      Manuscript received
      27 June 1950
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