• Kinetic studies in ester hydrolysis - Part V. The influence of solvent on the reaction

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/032/05/0330-0337

    • Keywords

       

      Dielectric Constant; Alkaline Hydrolysis; Carbonyl Oxygen; Transition Complex; Acid Catalysed

    • Abstract

       

      The influence of solvent on the rates of acid catalysed and alkaline hydrolysis of ethyl acetate has been discussed, the main factor taken into consideration being dielectric constant of the medium. Considerable light has been thrown on the precise role of the water molecule in alkaline hydrolysis. Specific solvent effects are also clearly noticeable since the reaction velocities, for both acid and alkaline hydrolysis, are more sensitive to changes in dielectric constant in acetone-water than in dioxane-water mixtures.

    • Author Affiliations

       

      P Madhavan Nair1 S V Anantakrishnan1

      1. Department of Chemistry, Madras Christian College, Tambaram
    • Dates

       
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