• The structure of ozone—An interpretation of its magnetic susceptibility

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/025/06/0520-0522

    • Keywords

       

      Ozone; Magnetic Susceptibility; Diamagnetic Susceptibility; Ozone Molecule; Multiplet Structure

    • Abstract

       

      Calculation of magnetic susceptibility for the different valence bond structures indicate that ozone should be diamagnetic, the susceptibility being about −18×10−6 while reported experimental values show that it is feebly paramagnetic in the liquid state, diamagnetic values being reported for the gaseous state. The possible causes of the discrepancy and a comparison with oxygen are discussed. The magnetic behaviour may be considered to conform to what may be expected from other physical properties of ozone.

    • Author Affiliations

       

      S V Anantakrishnan1

      1. Department of Chemistry, Madras Christian College, Tambaram
    • Dates

       
  •  

© 2022-2023 Indian Academy of Sciences, Bengaluru.