The structure of ozone—An interpretation of its magnetic susceptibility
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Calculation of magnetic susceptibility for the different valence bond structures indicate that ozone should be diamagnetic, the susceptibility being about −18×10−6 while reported experimental values show that it is feebly paramagnetic in the liquid state, diamagnetic values being reported for the gaseous state. The possible causes of the discrepancy and a comparison with oxygen are discussed. The magnetic behaviour may be considered to conform to what may be expected from other physical properties of ozone.
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