• Raman effect and hydrogen bonds - Part I. Mixtures of esters and acceptor molecules

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/014/05/0593-0603

    • Keywords

       

      Hydrogen Bond; Coumarin; Hydrogen Bond Formation; Cinnamate; Phenyl Propionate

    • Abstract

       

      A brief survey of the existing literature on hydrogen bonds is made. The advantages of employing the Raman effect for investigations in this field are discussed. The results not only supplement those obtained from infra-red studies but they become more definite, particularly when such groups as the C=O, which yield sharp Raman lines, are employed.

      Hydrogen bond formation between various esters as donor molecules and phenol, alcohols and chloroform as acceptor molecules has been studied and the results are presented in this paper. The changes in the C=O frequencies are classified. It is shown that there are large variations in the strengths of hydrogen bonds. The generalization that the strengths of hydrogen bonds depend on the anionoid power of the donor and the cationoid power of the acceptor atoms is made as a logical consequence of the mechanism of hydrogen bonds and is supported by the experimental results that are recorded.

    • Author Affiliations

       

      G V L N Murty1 T R Seshadri1

      1. Department of Chemistry, Andhra University, Waltair
    • Dates

       
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