1. Home
    2. Journals
    3. Proceedings – Section A
    4. Volume 12
    5. Issue 3

    • The kinetics of the olefin-bromine reaction - Part I. The dark reaction in acetic acid solution

      S V Anantakrishnan R Venkataraman

      Volume 12 Issue 3 September 1940 pp 290-305

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/seca/012/03/0290-0305

    • Keywords

       

      Bromine; Acrylic Acid; Induction Period; Acetic Acid Solution; Glutaric Acid

    • Abstract

       

      The kinetics of the olefin-bromine reaction has been studied in acetic acid solution using three related aliphatic monobasic acids. The course of the reaction clearly indicates a chain mechanism. It is found that the reaction is of the first order with respect to the olefin and the influence of the catalyst hydrogen bromide is pronounced, the experimental evidence favouring a complex formation between olefin and catalyst.

    • Author Affiliations

       

      S V Anantakrishnan1 R Venkataraman1

      1. Department of Chemistry, Annamalai University, Annamalainagar

    • Dates

       
      Published
      September 1940
      Manuscript received
      20 July 1940
  •  

© 2022-2023 Indian Academy of Sciences, Bengaluru.

Contact | Site index