Properties of concrete are strongly dependent on its pore structure features, porosity being an important one among them. This study deals with developing an understanding of the pore structure-compressive strength relationship in concrete. Several concrete mixtures with different pore structures are proportioned and subjected to static compressive tests. The pore structure features such as porosity, pore size distribution are extracted using mercury intrusion porosimetry technique. A statistical model is developed to relate thecompressive strength to relevant pore structure features.