• Role of virial coefficients in chemical reaction

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      https://www.ias.ac.in/article/fulltext/pram/095/0144

    • Keywords

       

      Thermodynamics; reaction rate constant; van’t Hoff equation; virial coefficients.

    • Abstract

       

      van’t Hoff equation relates equilibrium constant K of a chemical reaction to temperature T . Though the van’t Hoff plot (ln K vs. 1/T ) is linear, it is nonlinear for certain chemical reactions. In this work we attribute such observations to virial coefficients.

    • Author Affiliations

       

      P VIPIN1 R SANKARANARAYANAN

      1. Department of Physics, National Institute of Technology, Tiruchirappalli 620 015, India
    • Dates

       
  • Pramana – Journal of Physics | News

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