• Analytical evaluation of cesium emission lines using laser-induced breakdown spectroscopy

• # Fulltext

https://www.ias.ac.in/article/fulltext/pram/093/01/0002

• # Keywords

Laser-induced breakdown spectroscopy; emission; spectroscopy; cesium; linear dynamic range

• # Abstract

A laser-induced breakdown spectroscopy-based method has been successfully developed to quantify cesium (Cs) in solution using spectroscopically pure graphite planchets as a sample support. As Cs is a line-poor system, only five usable Cs atomic emission lines could be found and characterised by employing high-resolution system. The calibration curves of these emission lines were constructed under optimised experimental conditions. The analytical properties of these calibration curves were evaluated based on the usable dynamic range, $R^{2}$ of fitting, root mean square error cross-validation and limit of detection (LOD). The dynamic ranges of these five lines were found to be in correlation with the energy level involved in the transition. An LOD of 4 ppm was obtained using Cs(I) 852.11-nm line, which corresponds to 0.16 $\mu$g of Cs on the planchet. Based on the cross-validation approach, the best accuracy and precision ($\sim$6%) were obtained for 852.11 nm in >3000 ppm solutions, and the same is $\sim$8% for 672.33 nm and 697.33 nm in high concentrated solution of Cs.

• # Author Affiliations

1. Fuel Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 094, India
2. Homi Bhabha National Institute, Anushaktinagar, Mumbai 400 094, India

• # Pramana – Journal of Physics

Volume 96, 2022
All articles
Continuous Article Publishing mode

• # Editorial Note on Continuous Article Publication

Posted on July 25, 2019