We present a practical design of novel photonic crystal fibre (PCF) to investigate the nonlinear propagation of femtosecond pulses for the application of optical coherence tomography (OCT) based on supercontinuum generation (SCG) process. In addition, this paper contains a brief introduction of the physical phenomena of soliton and SCG. Typically, here we discuss how the ultrabroadband radiation in PCF can be generated by SCG through various nonlinear effects of the fibre. To accomplish the proposed aim, we put forth liquid core PCF (LCPCF) structure filled with chloroform for OCT measurements of the eye. From the proposed design, we observe that proposed LCPCFs with liquid material exhibit significant broadened wavelength spectrum with low input pulse energy over small propagation distances for the OCT application.