The fission decay of highly neutron-rich uranium isotopes is investigated which shows interesting new features in the barrier properties and neutron emission characteristics in the fission process. ²³³U and ²³⁵U are the nuclei in the actinide region in the beta stability valley which are thermally fissile and have been mainly used in reactors for power generation. The possibility of occurrence of thermally fissile members in the chain of neutron-rich uranium isotopes is examined here. The neutron number $N = 162$ or 164 has been predicted to be magic in numerous theoretical studies carried out over the years. The series of uranium isotopes around it with $N = 154-172$ are identified to be thermally fissile on the basis of the fission barrier and neutron separation energy systematics; a manifestation of the close shell nature of $N = 162$ (or 164). We consider here the thermal neutron fission of a typical representative ²⁴⁹U nucleus in the highly neutron-rich region. Semiempirical study of fission barrier height and width shows that ²⁵⁰U nucleus is stable against spontaneous fission due to increase in barrier width arising out of excess neutrons. On the basis of the calculation of the probability of fragment mass yields and the microscopic study in relativistic mean field theory, this nucleus is shown to undergo exotic decay mode of thermal neutron fission (multi-fragmentation fission) whereby a number of prompt scission neutrons are expected to be simultaneously released along with the two heavy fission fragments. Such properties will have important implications in stellar evolution involving 𝑟-process nucleosynthesis.