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      https://www.ias.ac.in/article/fulltext/pram/067/02/0389-0394

    • Keywords

       

      Non-linearity parameter; molecular radius; free length; intermolecular interactions

    • Abstract

       

      Computation of non-linearity parameter (B/A), molecular radius (rm) and intermolecular free length (Lf) for H2O, C6H6, C6H12, CH3OH, C2H5OH and their deuterium-substituted compounds have been carried out at four different temperatures, viz., 293.15, 303.15, 313.15 and 323.15 K. The aim of the investigation is an attempt to study the isotopic effects on the non-linearity parameter and the physicochemical properties of the liquids, which in turn has been used to study their effect on the intermolecular interactions produced thereof.

    • Author Affiliations

       

      Ranjan Dey1 Arvind K Singh2 N K Soni2 B S Bisht3 J D Pandey2

      1. Department of Chemistry, BITS-Pilani, Goa Campus, Zuarinagar - 403 726, India
      2. Department of Chemistry, University of Allahabad, Allahabad - 211 002, India
      3. Government Post Graduate Degree College, Lansdowne - 246 193, Uttaranchal

    • Dates

       
      Published
      August 2006
      Manuscript received
      19 September 2005
      Manuscript revised
      10 February 2006
      Accepted
      15 April 2006

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