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      https://www.ias.ac.in/article/fulltext/pram/044/05/0461-0470

    • Keywords

       

      Infrared spectrum; Raman spectrum; hydrogen bonding

    • Abstract

       

      The infrared and Raman spectra of NaNi2OH(H2O)(MoO4)2 and NaZn2OH (H2O)(MoO4)2 and their partially deuterated analogues are recorded and analysed on the basis of vibrations of MoO42− tetrahedra and H2O molecules. The MoO42− groups are found to be more distorted in NaNi2OH(H2O)(MoO4)2 than in the other compound. Bands indicating the presence of H3O+ ions are not observed in NaZn2OH(H2O)(MoO4)2 ruling out the possibility of the formulation of NaZn2OHO(MoO3OH)2. Hydrogen bonds of medium strength are present in both the compounds.

    • Author Affiliations

       

      R Ratheesh1 G Suresh1 V U Nayar1

      1. Department of Physics, University of Kerala, Kariavattom, Trivandrum - 695 581, India
    • Dates

       
  • Pramana – Journal of Physics | News

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