• A translational energy spectrometer to probe interatomic potentials: Dissociation dynamics of CO2+ ions

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      https://www.ias.ac.in/article/fulltext/pram/041/03/0271-0283

    • Keywords

       

      Ion-molecule collisions; translational energy spectrometer; dissociation; energy loss spectra

    • Abstract

       

      A new ion translational energy spectrometer has been developed to carry out low-energy, gas-phase ion-molecule collision experiments which aim to probe molecular potential energy surfaces. The collisional technique employed relates small changes in the kinetic energy of a projectile ion after it has undergone collision with a static neutral atom/molecule to changes in the overall potential energy of the collision system; information can be furnished about the interaction potential between the projectile and the target. First measurements are reported of a high resolution target excitation spectrum obtained in 1.8 keV collisions of H2+ ions with N2. New results pertaining to collision-induced dissociation of CO2+ ions are presented and discussed in terms of potential functions of low-lying electronic states of the molecular ion.

    • Author Affiliations

       

      M Krishnamurthy1 U T Raheja1 D Mathur1

      1. Atomic and Molecular Sciences Laboratory, Tata Institute of Fundamental Research, Homi Bhabha Road, Bombay - 400 005, India
    • Dates

       
  • Pramana – Journal of Physics | News

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