Two photon laser optogalvanic spectrum of theD-X system of HgBr molecule has been recorded using Nd-YAG laser pumped dye laser for the first time. A large number of new bands involving higher vibrational levels have been observed. Isotopic heads due to the two bromine isotopes have been observed and used in fixing the vibrational assignment. Vibrational constants for theX andD states of the two isotopic molecules have been determined.
Volume 96, 2022
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