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    • Measurement of diffusion coefficients of thallium ion in H2O and D2O systems at different concentrations

      A Das S N Changdar

      Volume 39 Issue 4 October 1992 pp 317-321

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/pram/039/04/0317-0321

    • Keywords

       

      Diffusion coefficient; heavy water; sliding cell method; radioisotopes; water structure

    • Abstract

       

      Sliding cell method, developed in our laboratory, has been used to measure the inter diffusion coefficient of thallium ion in thallous sulphate solution over a wide concentration range using both water and heavy water as solvent at 35°C. The results have been analysed from the point of view of both ion-ion and ion-solvent interactions. The comparison of the diffusivities of the same ion in D2O and H2O electrolyte solutions at the same temperature indicate that the addition of salt affects the two solvents differently.

    • Author Affiliations

       

      A Das1 S N Changdar1

      1. Department of Physics, Bose Institute, 93/1, APC Road, Calcutta - 700 009, India

    • Dates

       
      Published
      October 1992
      Manuscript received
      2 December 1991
      Manuscript revised
      2 May 1992

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