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    • Temperature variation of the Debye-Waller factors of metal and halide ions in CsCl and CsBr powders by X-ray diffraction. II. Debye-Waller factors of Cs+ and Br− ions in CsBr from room temperature to 78.2°K

      V Ganesan K S Girirajan

      Condensed Matter Physics Volume 30 Issue 4 April 1988 pp 337-340

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/pram/030/04/0337-0340

    • Keywords

       

      Cryostat; powder diffraction; Debye-Waller factors; SFLS program; lattice dynamics; caesium bromide; thermal diffuse scattering correction

    • Abstract

       

      The temperature variation of the Debye-Waller factors of Cs+ and Br− ions in CsBr powder has been studied using powder X-ray diffraction. The integrated intensities of the Bragg peaks at different temperatures have been obtained. These results have been verified by structure factor least squares refinement program. Theoretical shell model lattice dynamical calculations have been done using a 7-parameter model in the harmonic approximation and the values compared with the present X-ray measurements. The observed intensities have been corrected for first order thermal diffuse scattering.

    • Author Affiliations

       

      V Ganesan1 K S Girirajan1

      1. Department of Crystallography and Biophysics, University of Madras, Guindy Campus, Madras - 600 025, India

    • Dates

       
      Published
      April 1988
      Manuscript received
      16 February 1987
      Manuscript revised
      29 December 1987

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